Lithium Batteries and other Electrochemical Storage Systems

The lead-acid accumulator was introduced in the middle of the 19th Century, the diverse variants of nickel accumulators between the beginning and the end of the 20th Century. Although old, these technologies are always very present on numerous markets. Unfortunately they are still not used in optimal conditions, often because of the misunderstanding of the internal electrochemical phenomena. This book will show that batteries are complex systems, made commercially available thanks to considerable amounts of scientific research, empiricism and practical knowledge. However, the design of batteries is not fixed; it is subject to constant developments as a result of user feedback and validation processes which are often long and fastidious. This book attempts to show that it is not possible to consider a family of batteries as having fixed, applicable properties and characteristics whatever the application and the technology used in their manufacture. For this reason, the authors have chosen to present the fundamental electrochemical and chemical phenomena involved in as simple and as clear a way as possible. It is essential to be aware of these mechanisms in order to develop suitable theoretical models. This work will be of particular interest to those working in the field of electrical engineering and to industrialists, the final users of these technologies. It will also be of interest to electrochemists, as experts in lead or nickel batteries are becoming fewer and farther between, and their knowledge and practical skills are steadily being lost. Contents Part 1. Universal Characteristics of Batteries 1. Definitions and Methods of Measurement. Part 2. Lead–Acid Batteries 2. The Operation of Lead–Acid Batteries. 3. Internal Composition and Types of Lead–Acid Batteries. 4. Lead Batteries: Main Characteristics. 5. Manufacturing Starting, Lighting and Ignition Batteries. Part 3. Introduction to Nickel-Based Batteries 6. Nickel–Cadmium Batteries. 7. Nickel–Metal Hydride Batteries. 8. Other Nickel-Based Batteries.

The electrochemical storage of energy has become essential in assisting the development of electrical transport and use of renewable energies. French researchers have played a key role in this domain but Asia is currently the market leader. Not wanting to see history repeat itself, France created the research network on electrochemical energy storage (RS2E) in 2011. This book discusses the launch of RS2E, its stakeholders, objectives, and integrated structure that assures a continuum between basic research, technological research and industries. Here, the authors will cover the technological advances as well as the challenges that must still be resolved in the field of electrochemical storage, taking into account sustainable development and the limited time available to us.

Explains the current state of the science and points the way to technological advances First developed in the late 1980s, lithium-ion batteries now power everything from tablet computers to power tools to electric cars. Despite tremendous progress in the last two decades in the engineering and manufacturing of lithium-ion batteries, they are currently unable to meet the energy and power demands of many new and emerging devices. This book sets the stage for the development of a new generation of higher-energy density, rechargeable lithium-ion batteries by advancing battery chemistry and identifying new electrode and electrolyte materials. The first chapter of Lithium Batteries sets the foundation for the rest of the book with a brief account of the history of lithium-ion battery development. Next, the book covers such topics as: Advanced organic and ionic liquid electrolytes for battery applications Advanced cathode materials for lithium-ion batteries Metal fluorosulphates capable of doubling the energy density of lithium-ion batteries Efforts to develop lithium-air batteries Alternative anode rechargeable batteries such as magnesium and sodium anode systems Each of the sixteen chapters has been contributed by one or more leading experts in electrochemistry and lithium battery technology. Their contributions are based on the latest published findings as well as their own firsthand laboratory experience. Figures throughout the book help readers understand the concepts underlying the latest efforts to advance the science of batteries and develop new materials. Readers will also find a bibliography at the end of each chapter to facilitate further research into individual topics. Lithium Batteries provides electrochemistry students and researchers with a snapshot of current efforts to improve battery performance as well as the tools needed to advance their own research efforts.

Lithium secondary batteries have been key to mobile electronics since 1990. Large-format batteries typically for electric vehicles and energy storage systems are attracting much attention due to current energy and environmental issues. Lithium batteries are expected to play a central role in boosting green technologies. Therefore, a large number of scientists and engineers are carrying out research and development on lithium secondary batteries. The book is written in a straightforward fashion suitable for undergraduate and graduate students, as well as scientists, and engineers starting out in the field. The chapters in this book have been thoroughly edited by a collective of experts to achieve a cohesive book with a consistent style, level, and philosophy. They cover a wide range of topics, including principles and technologies of key materials such as the cathode, anode, electrolyte, and separator. Battery technologies such as design, manufacturing processes, and evaluation methods as well as applications are addressed. In addition, analytical methods for determining electrochemical and other properties of batteries are also included. Hence, this book is a must-have for everyone interested in obtaining all the basic information on lithium secondary batteries.

The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basics of thermodynamics and electrode kinetics to transport phenomena in electrolytes, metals, and semiconductors. Newly updated and expanded, the Third Edition covers important new treatments, ideas, and technologies while also increasing the book's accessibility for readers in related fields. Rigorous and complete presentation of the fundamental concepts In-depth examples applying the concepts to real-life design problems Homework problems ranging from the reinforcing to the highly thought-provoking Extensive bibliography giving both the historical development of the field and references for the practicing electrochemist.

This new volume covers the latest developments in the field of electrochemistry. It addresses a variety of topics including new materials development, materials synthesis, processing, characterization, property measurements, structure-property relationships, and device performance. A broader view of various electrochemical energy conversion devices make this book a critical read for scientists and engineers working in related fields. Papers from the symposium at the 102nd Annual Meeting of The American Ceramic Society, April 29-May 3, 2000, Missouri and the 103rd Annual Meeting, April 22-25, 2001, Indiana.

Rechargeable Batteries with high energy density are in great demand as energy sources for various purposes, e.g. handies, zero emission electric vehicles, or load leveling in electric power. Lithium batteries are the most promising to fulfill such needs because of their intrinsic discharbe voltage with relatively light weight. This volume has been conceived keeping in mind selected fundamental topics together with the characteristics of the lithium ion battery on the market. It is thus a comprehensive overview of the new challenges facing the further development of lithium ion batteries from the standpoint of both materials science and technology. It will be useful for any scientist involved in the research and development of batteries in academia and industry, and also for graduate students entering the field, since it covers important topics from both fundamental and application points of view.

A guide to the biological control over electronic systems that lead the way to wearable electronics and improved drug delivery In recent years, this area of electrochemical systems has developed rapidly and achieved significant progress. Signal-Switchable Electrochemical Systems offers an overview to the wide-variety of switchable electrochemical systems and modified electrodes. The author—a noted researcher and expert on the topic—summarizes research efforts of many groups in a range of universities and countries. The book explores various types of external signals that are able to modify electrode interfaces, for example electrical potential, magnetic field, light, as well as chemical and biochemical inputs. Multifunctional properties of the modified interfaces allow their responses to complex combinations of external signals. These are integrated with unconventional biomolecular computing systems logically processing multiple biochemical signals. This approach allows the biological control over electronic systems. The text explores the applications in different areas, including unconventional computing, biofuel cells and signal-triggered molecular release in electrochemical systems. This important guide: Provides an overview to the biological control over electronic systems and examines the key applications in biomedicine, electrochemical energy conversion and signal-processing Offers an important text written by a highly cited researcher and pioneer in the field Contains a summary of research efforts of an international panel of scholars representing various universities and countries Presents a groundbreaking book that provides an introduction to this interdisciplinary field Written for scientists working with electrochemical systems and applications with signal-responsive materials, Signal-Switchable Electrochemical Systems presents an overview of the multidisciplinary field of adaptable signal-controlled electrochemical systems and processes and highlights their key aspects and future perspectives.

A comprehensive guide to the reuse and recycling of lithium-ion power batteries—fundamental concepts, relevant technologies, and business models Reuse and Recycling of Lithium-Ion Power Batteries explores ways in which retired lithium ion batteries (LIBs) can create long-term, stable profits within a well-designed business operation. Based on a large volume of experimental data collected in the author’s lab, it demonstrates how LIBs reuse can effectively cut the cost of Electric Vehicles (EVs) by extending the service lifetime of the batteries. In addition to the cost benefits, Dr. Guangjin Zhao discusses how recycling and reuse can significantly reduce environmental and safety hazards, thus complying with the core principles of environment protection: recycle, reuse and reduce. Offering coverage of both the fundamental theory and applied technologies involved in LIB reuse and recycling, the book's contents are based on the simulated and experimental results of a hybrid micro-grid demonstration project and recycling system. In the opening section on battery reuse, Dr. Zhao introduces key concepts, including battery dismantling, sorting, second life prediction, re-packing, system integration and relevant technologies. He then builds on that foundation to explore advanced topics, such as resource recovery, harmless treatment, secondary pollution control, and zero emissions technologies. Reuse and Recycling of Lithium-Ion Power Batteries: • Provides timely, in-depth coverage of both the reuse and recycling aspects of lithium-ion batteries • Is based on extensive simulation and experimental research performed by the author, as well as an extensive review of the current literature on the subject • Discusses the full range of critical issues, from battery dismantling and sorting to secondary pollution control and zero emissions technologies • Includes business models and strategies for secondary use and recycling of power lithium-ion batteries Reuse and Recycling of Lithium-Ion Power Batteries is an indispensable resource for researchers, engineers, and business professionals who work in industries involved in energy storage systems and battery recycling, especially with the manufacture and use (and reuse) of lithium-ion batteries. It is also a valuable supplementary text for advanced undergraduates and postgraduate students studying energy storage, battery recycling, and battery management.

This proceedings focuses on both the scientific and technological aspects of fuel cells and high energy density batteries including solid oxide; proton exchange membrane; and direct methanol fuel cells; lithium-ion batteries; oxide-ion electrolytes; proton conductors; mixed ionic-electronic conductors; electrocatalysts; new materials development; and other related solid state and electrochemical aspects including supercapacitors and oxygen separation membranes.