Catalytic Process Development for Renewable Materials

The subject of advanced materials in catalysisbrings together recent advancements in materials synthesis and technologies to the design of novel and smart catalysts used in the field of catalysis. Nanomaterials in general show an important role in chemical processing as adsorbents, catalysts, catalyst supports and membranes, and form the basis of cutting-edge technology because of their unique structural and surface properties. Advanced Catalytic Materials is written by a distinguished group of contributors and the chapters provide comprehensive coverage of the current literature, up-to-date overviews of all aspects of advanced materials in catalysis, and present the skills needed for designing and synthesizing advanced materials. The book also showcases many topics concerning the fast-developing area of materials for catalysis and their emerging applications. The book is divided into three parts: Nanocatalysts – Architecture and Design; Organic and Inorganic Catalytic Transformations; and Functional Catalysis: Fundamentals and Applications. Specifically, the chapters discuss the following subjects: Environmental applications of multifunctional nanocomposite catalytic materials Transformation of nanostructured functional precursors using soft chemistry Graphenes in heterogeneous catalysis Gold nanoparticles-graphene composites material for catalytic application Hydrogen generation from chemical hydrides Ring-opening polymerization of poly(lactic acid) Catalytic performance of metal alkoxides Cycloaddition of CO2 and epoxides over reusable solid catalysts Biomass derived fine chemicals using catalytic metal bio-composites Homoleptic metal carbonyls in organic transformation Zeolites: smart materials for novel, efficient, and versatile catalysis Optimizing zeolitic catalysis for environmental remediation

One of the main challenges facing the chemical industry is the transition to sustainable operations. Industries are taking initiatives to reduce resource intensities or footprints, and by adopting safer materials and processes. Such efforts need to be supported by techniques that can quantify the broad economic and environmental implications of industrial operations, retrofi t options and provide new design alternatives. This contemporary overview focuses on cradle-to-grave life cycle assessments of existing or conceptual processes for producing valueadded fuels, chemicals, and/or materials from renewable agricultural residues, plant-derived starches and oils, lignocellulosic biomass, and plant-based industrial processing wastes. It presents the key concepts, systems, and technologies, with an emphasis on new feedstocks for the chemical industry. Each chapter uses common themes of specifi c raw materials, thus forming a natural progression throughout the book. The result is coverage from a wide range of perspectives, emphasizing not only the technical issues but also considering the market place and socio-economic aspects.

This unique handbook provides a vivid multidisciplinary dimension through technological perspectives to present cutting-edge research in the field of natural coloration and finishing. The 20 chapters are divided in to four parts: Substrates for coloration and finishing; renewable colorants and their applications; advanced materials and technologies for coloration and finishing; sustainability. Among the topics included in the Handbook of Renewable Materials for Coloration and Finishing are: The systematic discussion on the suitability, physical, chemical and processing aspects of substrates for coloration and finishing Bio-colorant’s application as photosensitizers for dye sensitized solar cells Animal based natural dyes Natural dyes extraction and dyeing methodology Application of natural dyes to cotton and jute textiles Sol-gel flame retardant and/or antimicrobial finishings for cellulosic textiles Rot resistance and antimicrobial finish of cotton khadi fabrics Advanced materials and technologies for antimicrobial finishing of cellulosic textiles

A real-world guide to the production and manufacturing of biopharmaceuticals While much has been written about the science of biopharmaceuticals, there is a need for practical, up-to-date information on key issues at all stages of developing and manufacturing commercially viable biopharmaceutical drug products. This book helps fill the gap in the field, examining all areas of biopharmaceuticals manufacturing, from development and formulation to production and packaging. Written by a group of experts from industry and academia, the book focuses on real-world methods for maintaining product integrity throughout the commercialization process, clearly explaining the fundamentals and essential pathways for all development stages. Coverage includes: Research and early development phase–appropriate approaches for ensuring product stability Development of commercially viable formulations for liquid and lyophilized dosage forms Optimal storage, packaging, and shipping methods Case studies relating to therapeutic monoclonal antibodies, recombinant proteins, and plasma fractions Useful analysis of successful and failed products Formulation and Process Development Strategies for Manufacturing Biopharma-ceuticals is an essential resource for scientists and engineers in the pharmaceutical and biotech industries, for government and regulatory agencies, and for anyone with an interest in the latest developments in the field.

This useful, one-stop resource for understanding the most important issues in materials challenges in alternative and renewable energy. The logically organized and carefully selected articles give insight into materials challenges in alternative renewable energy and incorporate the latest developments related to materials challenges in alternative renewable energy, including hydrogen, batteries and energy storage materials, hydropower, and biomass.

This book describes recent progress in enzyme-driven green syntheses of industrially important molecules. The first three introductory chapters overview recent technological advances in enzymes and cell-based transformations, and green chemistry metrics for synthetic efficiency. The remaining chapters are directed to case studies in biotechnological production of pharmaceuticals (small molecules, natural products and biologics), flavors, fragrance and cosmetics, fine chemicals, value-added chemicals from glucose and biomass, and polymeric materials. The book is aimed to facilitate the industrial applications of this powerful and emerging green technology, and catalyze the advancement of the technology itself.

As naturally occurring and abundant sources of non-fossil carbon, lignin and lignans offer exciting possibilities as a source of commercially valuable products, moving away from petrochemical-based feedstocks in favour of renewable raw materials. Lignin can be used directly in fields such as agriculture, livestock, soil rehabilitation, bioremediation and the polymer industry, or it can be chemically modified for the fabrication of specialty and high-value chemicals such as resins, adhesives, fuels and greases. Lignin and Lignans as Renewable Raw Materials presents a multidisciplinary overview of the state-of-the-art and future prospects of lignin and lignans. The book discusses the origin, structure, function and applications of both types of compounds, describing the main resources and values of these products as carbon raw materials. Topics covered include: • Structure and physicochemical properties • Lignin detection methods • Biosynthesis of lignin • Isolation methods • Characterization and modification of lignins • Applications of modified and unmodified lignins • Lignans: structure, chemical and biological properties • Future perspectives This book is a comprehensive resource for researchers, scientists and engineers in academia and industry working on new possibilities for the application of renewable raw materials. For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs

The overall efficiency, effectiveness, and practicality of potential future energy sources and systems are directly related to many materials-related factors. This volume features 30 papers presented during the 2012 Materials Challenges in Alternative and Renewable Energy Conference. They cover the latest developments involving materials for alternative and renewable energy sources and systems, including batteries and energy storage, hydrogen, solar, wind, geothermal, biomass, and nuclear, as well as materials availability, the energy grid, and nanocomposites.

Discusses the growth mechanisms of tin whiskers and the effective mitigation strategies necessary to reduce whisker growth risks This book covers key tin whisker topics, ranging from fundamental science to practical mitigation strategies. The text begins with a review of the characteristic properties of local microstructures around whisker and hillock grains to identify why these particular grains and locations become predisposed to forming whiskers and hillocks. The book discusses the basic properties of tin-based alloy finishes and the effects of various alloying elements on whisker formation, with a focus on potential mechanisms for whisker suppression or enhancement for each element. Tin whisker risk mitigation strategies for each tier of the supply chain for high reliability electronic systems are also described. Discusses whisker formation factors including surface grain geometry, crystallographic orientation-dependent surface grain boundary structure, and the localization of elastic strain/strain energy density distribution Examines how whiskers and hillocks evolve in time through real-time studies of whisker growth with the scanning electron microscope/focused ion beaming milling (SEM/FIB) Covers characterization methods of tin and tin-based alloy finishes such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD) Reviews theories of mechanically-induced tin whiskers with case studies using pure tin and other lead-free finishes shown to evaluate the pressure-induced tin whiskers Mitigating Tin Whisker Risks: Theory and Practice is intended for the broader electronic packaging and manufacturing community including: manufacturing engineers, packaging development engineers, as well as engineers and researchers in high reliability industries.