Characterization of Solid Materials and Heterogeneous Catalysts. From Structure to Surface Reactivity

Presents s tate-of-the-art knowledge of heterogeneous catalysts including new applications in energy and environmental fields   This book focuses on emerging techniques in heterogeneous catalysis, from new methodology for catalysts design and synthesis, surface studies and operando spectroscopies, ab initio techniques, to critical catalytic systems as relevant to energy and the environment. It provides the vision of addressing the foreseeable knowledge gap unfilled by classical knowledge in the field.  Heterogeneous Catalysts: Advanced Design, Characterization and Applications   begins with an overview on the evolution in catalysts synthesis and introduces readers to facets engineering on catalysts; electrochemical synthesis of nanostructured catalytic thin films; and bandgap engineering of semiconductor photocatalysts. Next, it examines how we are gaining a more precise understanding of catalytic events and materials under working conditions. It covers bridging pressure gap in surface catalytic studies; tomography in catalysts design; and resolving catalyst performance at nanoscale via fluorescence microscopy. Quantum approaches to predicting molecular reactions on catalytic surfaces follows that, along with chapters on Density Functional Theory in heterogeneous catalysis; first principles simulation of electrified interfaces in electrochemistry; and high-throughput computational design of novel catalytic materials. The book also discusses embracing the energy and environmental challenges of the 21st century through heterogeneous catalysis and much more.  Presents recent developments in heterogeneous catalysis with emphasis on new fundamentals and emerging techniques Offers a comprehensive look at the important aspects of heterogeneous catalysis Provides an applications-oriented, bottoms-up approach to a high-interest subject that plays a vital role in industry and is widely applied in areas related to energy and environment  Heterogeneous Catalysts: Advanced Design, Characterization and Applications  is an important book for catalytic chemists, materials scientists, surface chemists, physical chemists, inorganic chemists, chemical engineers, and other professionals working in the chemical industry.

Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.

An authoritative reference on the processing and finishing of polymeric materials for scientists and practitioners Owing to their versatility and wide range of applications, polymeric materials are of great commercial importance. Manufacturing processes of commercial products are designed to meet the requirements of the final product and are influenced by the physical and chemical properties of the polymeric material used. Based on Wiley's renowned Encyclopedia of Polymer Science and Technology, Processing and Finishing of Polymeric Materials provides comprehensive, up-to-date details on the latest manufacturing technologies, including blending, compounding, extrusion,molding, and coating. Written by prominent scholars from industry, academia, and research institutions from around the globe, this reference features more than forty selected reprints from the Encyclopedia as well as new contributions, providing unparalleled coverage of such topics as: Additives Antistatic agents Bleaching Blowing agents Calendaring Casting Coloring processes Dielectric heating Electrospinning Embedding Processing and Finishing of Polymeric Materials is an ideal resource for polymer and materials scientists, chemists, chemical engineers, materials scientists, process engineers, and consultants, and serves as a valuable addition to libraries of chemistry, chemical engineering, and materials science in industry, academia, and government.

The recent rapid progress in wireless telecommunication, including the Internet of Things, 5th generation wireless systems, satellite broadcasting, and intelligent transport systems has increased the need for low-loss dielectric materials and modern fabrication techniques. These materials have excellent electrical, dielectric, and thermal properties and have enormous potential, especially in wireless communication, flexible electronics, and printed electronics. Microwave Materials and Applications discusses the methods commonly employed for measuring microwave dielectric properties, the various attempts reported to solve problems of materials chemistry and crystal structure, doping, substitution, and composite formation, highlighting the processing techniques, morphology influences, and applications of microwave materials whilst summarizing many of the recent technical research accomplishments in the area of microwave dielectrics and applications Chapters examine: Oxide ceramics for dielectric resonators and substrates HTCC, LTCC and ULTCC tapes for substrates Polymer ceramic composites for printed circuit boards Elastomer-ceramic composites for flexible electronics Dielectric inks EMI shielding materials Microwave ferrites A comprehensive Appendix presents the fundamental properties for more than 4000 low-loss dielectric ceramics, their composition, crystal structure, and their microwave dielectric properties. Microwave Materials and Applications presents a comprehensive view of all aspects of microwave materials and applications, making it useful for scientists, industrialists, engineers, and students working on current and emerging applications of wireless communications and consumer electronics.

An excellent overview of industrial carbon and graphite materials, especially their manufacture, use and applications in industry.
Following a short introduction, the main part of this reference deals with industrial forms, their raw materials, properties and manifold applications. Featuring chapters on carbon and graphite materials in energy application, and as catalysts. It covers all important classes of carbon and graphite, from polygranular materials to fullerenes, and from activated carbon to carbon blacks and nanoforms of carbon.
Indispensable for chemists and engineers working in such fields as steel, aluminum, electrochemistry, nanotechnology, catalyst, carbon fibres and lightweight composites.

A one-stop resource for both researchers and development engineers, this comprehensive handbook serves as a daily reference, replacing heaps of individual papers. This second edition features twenty percent more content with new chapters on battery characterization, process technology, failure mechanisms and method development, plus updated information on classic batteries as well as entirely new results on advanced approaches. The authors, from such leading institutions as the US National Labs and from companies such as Panasonic and Sanyo, present a balanced view on battery research and large-scale applications. They follow a distinctly materials-oriented route through the entire field of battery research, thus allowing readers to quickly find the information on the particular materials system relevant to their research.

Written by a group of acoustics and vibration specialists, this book studies the acoustic and vibrating phenomena that occur in diverse materials used for all kinds of purposes. The first part studies the fundamental aspects of propagation: analytical, numerical and experimental. The second part outlines industrial and medical applications. Covering a wide range of topics that associate materials science with acoustics, this will be of invaluable use to researchers, engineers, or practitioners in this field, as well as students in acoustics, physics, and mechanics.

Catalysts are increasingly used by chemists engaged in fine chemical synthesis within both industry and academia. Today, there exists a huge choice of high-tech catalysts, which add enormously to the repertoire of synthetic possibilities. However, catalysts are occasionally capricious, sometimes difficult to use and almost always require both skill and experience in order to achieve optimal results. This series aims to be a practical help for advanced undergraduate, graduate and postgraduate students, as well as experienced chemists in industry and academia working in organic and organometallic synthesis. The series features: * Tested and validated procedures. * Authoritative reviews on classes of catalysts. * Assessments of all types of catalysts. * Expertise from the Leverhulme Centre for Innovative Catalysis, Liverpool, UK. The review section in the first volume of the series contains a report by Stanley M. Roberts on the integration of biotransformations into the catalyst portfolio. The procedure section contains a wide variety of synthetic protocols, such as epoxidations of unsaturated ketones and esters, asymmetric reductions of carbon-oxygen double bonds, asymmetric hydrogenations of carbon-carbon double bonds and other types of reaction. The featured catalysts include a wide range of different materials such as poly-D-leucine, D-fructose-based dioxiranes, oxaborolidine borane, some important titanium and ruthenium complexes as well as baker's yeast. For each reaction there are one or several detailed protocols on how to prepare and employ the various catalysts.

This book presents all the theoretical and practical basements of heterogeneous kinetics and reactivity of solids. It applies the new concepts of reactivity and spatial function, introduced by the author, for both nucleation and growth processes, with a unified presentation of the reactivity of bulk and powder solids, including gas-solid reactions, thermal decompositions, solid-solid reactions, reactions of solid solutions, and coalescence of solid grains. It also contains many exercises and problems with solutions included, allowing readers to understand and use all the concepts and methods discussed therein.

This essential resource consists of a series of critical reviews written by leading scientists, summarising the progress in the field of conjugated thiophene materials. It is an application-oriented book, giving a chemists’ point of view on the state-of-art and perspectives of the field. While presenting a comprehensive coverage of thiophene-based materials and related applications, the aim is to show how the rational molecular design of materials can bring a new breadth to known device applications or even aid the development of novel application concepts. The main topics covered include synthetic methodologies to thiophene-based materials (including the chemistry of thiophene, preparation of oligomers and polymerisation approaches) and the structure and physical properties of oligo- and polythiophenes (discussion of structural effects on electronic and optical properties). Part of the book is devoted to the optical and semiconducting properties of conjugated thiophene materials for electronics and photonics, and the role of thiophene-based materials in nanotechnology.