Fundamental Concepts in Heterogeneous Catalysis

Written by one of the world's leading experts on the topic, this advanced textbook is the perfect introduction for newcomers to this exciting field. Concise and clear, the text focuses on such key aspects as kinetics, reaction mechanism and surface reactivity, concentrating on the essentials. The author also covers various catalytic systems, catalysis by design, and activation-deactivation. A website with supplementary material offers additional figures, original material and references.

This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved.

In the past 12 years since its publication, Concepts of Modern Catalysis and Kinetics has become a standard textbook for graduate students at universities worldwide. Emphasizing fundamentals from thermodynamics, physical chemistry, spectroscopy, solid state chemistry and quantum chemistry, it introduces catalysis from a molecular perspective, and stresses how it is interwoven with the field of reaction kinetics. The authors go on to explain how the world of reacting molecules is connected to the real world of industry, by discussing the various scales (nano – micro – macro) that play a role in catalysis. Reflecting the modern-day focus on energy supplies, this third edition devotes attention to such processes as gas-to-liquids, coal-to-liquids, biomass conversion and hydrogen production. From reviews of the prior editions: 'Overall, this is a valuable book that I will use in teaching undergraduates and postgraduates.' (Angewandte Chemie – I. E.) '…this excellent book is highly recommended to students at technical universities, but also entrants in chemical industry. Furthermore, this informative handbook is also a must for all professionals in the community.' (AFS) 'I am impressed by the coverage of the book and it is a valuable addition to the catalysis literature and I highly recommend purchase' (Energy Sources)

Until now, the literature has offered a rather limited approach to the use of fundamental kinetics and their application to catalytic reactions. Subsequently, this book spans the full range from fundamentals of kinetics and heterogeneous catalysis via modern experimental and theoretical results of model studies to their equivalent large-scale industrial production processes. The result is key knowledge for students at technical universities and professionals already working in industry. '… such an enterprise will be of great value to the community, to professionals as well as graduate and undergraduate students attempting to move into the field of modern catalysis and kinetics. I strongly recommend you publish this book based on the proposal.' – Prof. Dr. G. A. Samorjai, University of California 'Both authors are well respected specialists, with a very long record of original top-quality work and an international reputation. A book from these authors will be considered an authoritative piece of work, I definitely support this project and I am looking forward to use the book when published.' – Prof. Dr. D. E. Resasco, University of Oklahoma 'I wholly support the proposed project. The authors are very competent young colleagues and there is a real need for such a textbook' – Prof. Dr. G. Ertl, Fritz-Haber-Institut, Max-Planck-Gesellschaft, Berlin

Catalysis in Electrochemistry: From Fundamental Aspects to Strategies for Fuel Cell Development is a modern, comprehensive reference work on catalysis in electrochemistry, including principles, methods, strategies, and applications. It points out differences between catalysis at gas/surfaces and electrochemical interfaces, along with the future possibilities and impact of electrochemical science on energy problems. This book contributes both to fundamental science; experience in the design, preparation, and characterization of electrocatalytic materials; and the industrial application of electrocatalytic materials for electrochemical reactions. This is an essential resource for scientists globally in academia, industry, and government institutions.

Nanocatalysis has emerged as a field at the interface between homogeneous and heterogeneous catalysis and offers unique solutions to the demanding requirements for catalyst improvement. Heterogeneous catalysis represents one of the oldest commercial applications of nanoscience and nanoparticles of metals, semiconductors, oxides, and other compounds have been widely used for important chemical reactions. The main focus of this fi eld is the development of well-defined catalysts, which may include both metal nanoparticles and a nanomaterial as the support. These nanocatalysts should display the benefits of both homogenous and heterogeneous catalysts, such as high efficiency and selectivity, stability and easy recovery/recycling. The concept of nanocatalysis is outlined in this book and, in particular, it provides a comprehensive overview of the science of colloidal nanoparticles. A broad range of topics, from the fundamentals to applications in catalysis, are covered, without excluding micelles, nanoparticles in ionic liquids, dendrimers, nanotubes, and nanooxides, as well as modeling, and the characterization of nanocatalysts, making it an indispensable reference for both researchers at universities and professionals in industry.

A comprehensive overview covering the principles and preparation of catalysts, as well as reactor technology and applications in the field of organic synthesis, energy production, and environmental catalysis. Edited and authored by renowned and experienced scientists, this reference focuses on successful reaction procedures for applications in industry. Topics include catalyst preparation, the treatment of waste water and air, biomass and waste valorisation, hydrogen production, oil refining as well as organic synthesis in the presence of heterogeneous and homogeneous catalysts and continuous-flow reactions. With its practical relevance and successful methodologies, this is a valuable guide for chemists at universities working in the field of catalysis, organic synthesis, pharmaceutical or green chemistry, as well as researchers and engineers in the chemical industry.

A comprehensive summary of theoretical and practical developments in LTE Heterogeneous Networks The last decade has witnessed the proliferation of mobile broadband data and the trend is likely to increase in the coming years. Current cellular networks are ill equipped to deal with this surge in demand. To satisfy user demand and maximize profits, a new paradigm to operate networks is needed. Heterogeneous networks, that deploy an overlay of small cells with limited coverage and transmit power, over a macro coverage area is the solution by providing capacity and coverage where it is needed. This book presents a comprehensive overview of small cell based heterogeneous networks within the framework of 3GPP LTE-Advanced which is the major enabler of current and future heterogeneous networks. The book first establishes the basics of LTE standards 8 -10. Wherever relevant, the underlying theory of wireless communications is explained and the signaling and protocol aspects of LTE Releases 8-10 are presented. Next the book presents a systematic study of the inter cell interference (eICIC and FeICIC) mechanisms that have been standardized in LTE releases 10 and 11 to mitigate the interference arising in heterogeneous networks. From simple blank subframe design and implementation, the book discusses more advanced transceiver signal processing and carrier aggregation (CA) based mechanisms to improve performance. Besides data, control channel enhancements such as enhanced PDCCH (ePDCCH) are also discussed. Subsequently the book discusses the possibility of base stations being allowed to coordinate to manage interference. This technique, called CoMP, has the potential of vastly improving network performance. However several practical challenges first have to be overcome before this potential can be realized. The book presents the different CoMP categories introduced in LTE release 11, the required signal processing and the changes that were introduced in Release-11 for supporting CoMP. The book then presents the state of the art developments in heterogeneous networks that are currently taking place in 3GPP with the initiation of Release 12. A whole array of new technologies have been introduced such as dynamic switching of small cells, new carrier types with reduced control signaling, dynamic reconfiguration of TDD-LTE, joint configuration of TDD and FDD via carrier aggregation and lastly advanced MIMO signal processing with three dimensional beamforming. All these technologies will work in unison leading to efficient operations of small cells. The authors thus comprehensively summarize the advances in heterogeneous networks over the last couple of years as reflected in various LTE releases and then look ahead at what to expect in the future. Fully illustrated throughout and with an accompanying website including Matlab code for simulating heterogeneous networks, LTE channel models, and References to 3GPP specifications, contributions, and updates on recent standardization activities. The authors, being involved in LTE standardization, are well placed to give an excellent view on this topic, including valuable background and design rationale. A comprehensive summary of wireless communications theory and practical developments in LTE heterogeneous networks. Authors are experts in this field and are active members in standardization proceedings, enabling up-to-date coverage of current developments Multiple case studies explain network design optimization of various heterogeneous network deployments. Accompanying website includes Matlab code for simulating heterogeneous networks, LTE channel models, and References to 3GPP specifications, contributions, and updates on recent standardization activities Essential reading for Engineers and practitioners in wireless industry.

ESSENTIAL CONCEPTS IN MRI A concise and complete introductory treatment of NMR and MRI Essential Concepts in MRI delivers the first comprehensive look at magnetic resonance imaging with a practical focus on nuclear magnetic resonance spectroscopy applications. The book includes the essential components of MRI and NMR and is written for anyone new to the field of MRI who seeks to gain a complete understanding of all four essential components of MRI: physics theory, instrumentation, spectroscopy, and imaging. Highly visual and including numerous full color figures that provide crucial graphical descriptions of key concepts discussed in the book, Essential Concepts in MRI includes discussions of quantitative and creative MRI, as well as spatial mapping in MRI and the effects of the field gradient and k-space imaging. The book also covers: A thorough introduction to essential concepts in nuclear magnetic resonance, including classical descriptions of NMR and quantum mechanical descriptions of NMR Comprehensive explorations of essential concepts in NMR instrumentation, including magnets, radio-frequency coils, transmitters, and receivers Practical discussions of essential concepts in NMR spectroscopy, including simple 1D spectroscopy, double resonance, and dipolar interactions in two-spin systems In-depth examinations of essential concepts in MRI, including the design of MRI pulse sequences and the elements of MRI instrumentation, with a special focus on quantitative MRI Essential Concepts in MRI is a must-read reference for upper-level undergraduate and postgraduate students in the physical and medical sciences, especially radiology, MRI, and imaging courses. It is also essential for students and researchers in the biomedical sciences and engineering.

An essential guide to the basic concepts that comprise the study of sociology with contributions from an international range of leading experts Core Concepts in Sociology is a comprehensive guide to the essential concepts relevant to the current study of the discipline and wider social science. The contributing authors cover a wide range of concepts that remain at the heart of sociology including those from its academic founding and others much more recent in their development. The text contains contributions from an international panel of leading figures in the field, utilizing their expertise on core concepts and presenting an accessible introduction for students. Drawing on the widest range of ideas, research, current literature and expert assessment, Core Concepts in Sociology contains over 90 concepts that represent the discipline. Coverage includes concepts ranging from aging to capitalism, democracy to economic sociology, epistemology to everyday life, media to risk, stigma and much more. This vital resource: Sets out the concepts that underpin the study of sociology and wider social science Contains contributions from an international panel of leading figures in the field Includes a comprehensive review of the basic concepts that comprise the foundation and essential development of the discipline Designed as a concise and accessible resource Written for students, researchers and wider professionals with an interest in the field of sociology, Core Concepts in Sociology offers a concise, affordable and accessible resource for studying the underpinnings of sociology and social science.