Greener Fischer-Tropsch Processes for Fuels and Feedstocks

The Fischer-Tropsch process is gaining recognition again due to the world-wide increase in energy needs and decrease in oil availability. The increasing interest in utilizing biomass as a potential renewable feedstock in energy generation is further supporting this development. The book covers the production and refining of Fischer-Tropsch syncrude to fuels and chemicals systematically and comprehensively, presenting a wealth of new knowledge and material. As such, it deals extensively with aspects of engineering, chemistry and catalysis. This handbook and ready reference adopts a fundamental approach, looking at the molecules and their transformation from feed to product. Numerous examples illustrate the possibilities and limitations of Fischer-Tropsch syncrude as feesdstock. Of great interest to everyone interested in refining – not just Fischer-Tropsch specialists. From the Contents: Fischer-Tropsch Facilities and Refineries at a Glance Production of Fischer-Tropsch Syncrude Industrial Fischer-Tropsch Facilities Synthetic Transportation Fuels Refining Technology Refinery Design

Examines all stages of fuel production, from feedstocks to finished products Exploring chemical structures and properties, this book sheds new light on the current science and technology of producing energy efficient and environmentally friendly fuels. Moreover, it explains the role of fuel-additives in the production cycle. This expertly written and organized guide to fuels and fuel-additives also presents requirements, rules and regulations, including US and EU standards governing automotive emissions, fuel quality and specifications, alternate fuels, biofuels, antioxidants, deposit control detergents/dispersants, stabilizers, corrosion inhibitors, and polymeric fuel-additives. Fuels and Fuel-Additives covers all stages and facets of the production of engine fuels as well as heating and fuel oils. The book begins with a quick portrait of the future of fuels and fuel production. Then, it sets forth the regulations controlling exhaust gas emissions and fuel quality from around the world. Next, the book covers: Processing of engine fuels derived from crude oil, including the production of blending components Production of alternative fuels Fuel-additives for automotive engines Blending of fuels Key properties of motor fuels and their effects on engines and the environment Aviation fuels The final chapter of the book deals with fuel oils and marine fuels. Each chapter is extensively referenced, providing a gateway to the primary and secondary literature in the field. At the end of the book, a convenient glossary defines all the key terms used in the book. Examining the full production cycle from feedstocks to final products, Fuels and Fuel-Additives is recommended for students, engineers, and scientists working in fuels and energy production.

Addresses materials, technology, and products that could help solve the global environmental crisis once commercialized This multidisciplinary book encompasses state-of-the-art research on the topics of Carbon Capture and Storage (CCS), and complements existing CCS technique publications with the newest research and reviews. It discusses key challenges involved in the CCS materials design, processing, and modeling and provides in-depth coverage of solvent-based carbon capture, sorbent-based carbon capture, membrane-based carbon capture, novel carbon capture methods, computational modeling, carbon capture materials including metal organic frameworks (MOF), electrochemical capture and conversion, membranes and solvents, and geological sequestration. Materials and Processes for CO2 Capture, Conversion and Sequestration offers chapters on: Carbon Capture in Metal-Organic Frameworks; Metal Organic Frameworks Materials for Post-Combustion CO2 Capture; New Progress of Microporous Metal-Organic Frameworks in CO2 Capture and Separation; In Situ Diffraction Studies of Selected Metal-Organic Framework (MOF) Materials for Guest Capture Applications; Electrochemical CO2 Capture and Conversion; Electrochemical Valorization of Carbon Dioxide in Molten Salts; Microstructural and Structural Characterization of Materials for CO2 Storage using Multi-Scale X-Ray Scattering Methods; Contribution of Density Functional Theory to Microporous Materials for Carbon Capture; and Computational Modeling Study of MnO2 Octahedral Molecular Sieves for Carbon Dioxide Capture Applications. Addresses one of the most pressing concerns of society—that of environmental damage caused by the greenhouse gases emitted as we use fossil fuels Covers cutting-edge capture technology with a focus on materials and technology rather than regulation and cost Highlights the common and novel CCS materials that are of greatest interest to industrial researchers Provides insight into CCS materials design, processing characterization, and computer modeling Materials and Processes for CO2 Capture, Conversion and Sequestration is ideal for materials scientists and engineers, energy scientists and engineers, inorganic chemists, environmental scientists, pollution control scientists, and carbon chemists.

Bioenergy and biofuels are generated from a wide variety of feedstock. Fuels have been converted from a wide range of sources from vegetable oils to grains and sugarcane. Second generation biofuels are being developed around dedicated, non-food energy crops, such as switchgrass and Miscanthus, with an eye toward bioenergy sustainability. Bioenergy Feedstocks: Breeding and Genetics looks at advances in our understanding of the genetics and breeding practices across this diverse range of crops and provides readers with a valuable tool to improve cultivars and increase energy crop yields. Bioenergy Feedstocks: Breeding and Genetics opens with chapters focusing primarily on advances in the genetics and molecular biology of dedicated energy crops. These chapters provide in-depth coverage of new, high-potential feedstocks. The remaining chapters provide valuable overview of breeding efforts of current feedstocks with specific attention paid to the development of bioenergy traits. Coverage in these chapters includes crops such as sorghum, energy canes, corn, and other grasses and forages. The final chapters explore the role of transgenics in bioenergy feedstock production and the development of low-input strategies for producing bioenergy crops. A timely collection of work from a global team of bioenergy researchers and crop scientists, Bioenergy Feedstocks: Breeding and Genetics is an essential reference on cultivar improvement of biomass feedstock crops.

Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals. Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances. Topics covered include: • The importance of biomass conversion to fuels • The role of pretreatment in biological and chemical conversion of biomass • Composition and structure of biomass, and recalcitrance to conversion • Fundamentals of biomass pretreatment at low, neutral and high pH • Ionic liquid and organosolv pretreatments to fractionate biomass • Comparative data for application of leading pretreatments and effect of enzyme formulations • Physical and chemical features of pretreated biomass • Economics of pretreatment for biological processing • Methods of analysis and enzymatic conversion of biomass streams • Experimental pretreatment systems from multiwell plates to pilot plant operations This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.

As the range of feedstocks, process technologies and products expand, biorefineries will become increasingly complex manufacturing systems. Biorefineries and Chemical Processes: Design, Integration and Sustainability Analysis presents process modelling and integration, and whole system life cycle analysis tools for the synthesis, design, operation and sustainable development of biorefinery and chemical processes. Topics covered include: Introduction: An introduction to the concept and development of biorefineries. Tools: Included here are the methods for detailed economic and environmental impact analyses; combined economic value and environmental impact analysis; life cycle assessment (LCA); multi-criteria analysis; heat integration and utility system design; mathematical programming based optimization and genetic algorithms. Process synthesis and design: Focuses on modern unit operations and innovative process flowsheets. Discusses thermochemical and biochemical processing of biomass, production of chemicals and polymers from biomass, and processes for carbon dioxide capture. Biorefinery systems: Presents biorefinery process synthesis using whole system analysis. Discusses bio-oil and algae biorefineries, integrated fuel cells and renewables, and heterogeneous catalytic reactors. Companion website: Four case studies, additional exercises and examples are available online, together with three supplementary chapters which address waste and emission minimization, energy storage and control systems, and the optimization and reuse of water. This textbook is designed to bridge a gap between engineering design and sustainability assessment, for advanced students and practicing process designers and engineers.

Sets the stage for large-scale production of biofuels and bio-based chemicals In response to diminishing supplies as well as the environmental hazards posed by fossil fuels and petrochemicals, interest and demand for green, sustainable biofuels and bio-based chemicals are soaring. Biomass may be the solution. It is an abundant carbon-neutral renewable feedstock that can be used for the production of fuels and chemicals. Currently, biorefineries use corn, soybeans, and sugarcane for bioethanol and biodiesel production; however, there are many challenges facing biorefineries, preventing biomass from reaching its full potential. This book provides a comprehensive review of bioprocessing technologies that use lignocellulosic biomass for the production of biofuels, biochemicals, and biopolymers. It begins with an overview of integrated biorefineries. Next, it covers: Biomass feedstocks, including sugar, starch, oil, and energy crops as well as microalgae Pretreatment technologies for lignocellulosic biomass Hydrolytic enzymes used in biorefineries for the hydrolysis of starch and lignocelluloses Bioconversion technologies for current and future biofuels such as ethanol, biodiesel, butanol, hydrogen, and biogas Specialty chemicals, building block chemicals, and biopolymers produced via fermentation Phytochemicals and functional food ingredients extracted from plant materials All the chapters have been written and edited by leading experts in bioprocessing and biorefining technologies. Contributions are based on a thorough review of the literature as well as the authors' firsthand experience developing and working with bioprocessing technologies. By setting forth the current state of the technology and pointing to promising new directions in research, Bioprocessing Technologies in Biorefinery for Sustainable Production of Fuels, Chemicals, and Polymers will enable readers to move towards large-scale, sustainable, and economical production of biofuels and bio-based chemicals.

A comprehensive and accessible presentation of probability and stochastic processes with emphasis on key theoretical concepts and real-world applications With a sophisticated approach, Probability and Stochastic Processes successfully balances theory and applications in a pedagogical and accessible format. The book’s primary focus is on key theoretical notions in probability to provide a foundation for understanding concepts and examples related to stochastic processes. Organized into two main sections, the book begins by developing probability theory with topical coverage on probability measure; random variables; integration theory; product spaces, conditional distribution, and conditional expectations; and limit theorems. The second part explores stochastic processes and related concepts including the Poisson process, renewal processes, Markov chains, semi-Markov processes, martingales, and Brownian motion. Featuring a logical combination of traditional and complex theories as well as practices, Probability and Stochastic Processes also includes: Multiple examples from disciplines such as business, mathematical finance, and engineering Chapter-by-chapter exercises and examples to allow readers to test their comprehension of the presented material A rigorous treatment of all probability and stochastic processes concepts An appropriate textbook for probability and stochastic processes courses at the upper-undergraduate and graduate level in mathematics, business, and electrical engineering, Probability and Stochastic Processes is also an ideal reference for researchers and practitioners in the fields of mathematics, engineering, and finance.

Plastics Materials and Processes: A Concise Encyclopedia is a resource for anyone with an interest in plastic materials and processes, from seasoned professionals to laypeople. Arranged in alphabetical order, it clearly explains all of the materials and processes as well as their major application areas and usages. Plastics Materials and Processes: A Concise Encyclopedia: Discusses and describes applications and practical uses of the materials and processes. Clear definitions and sufficient depth to satisfy the information seekers needs

Crystal growth technology involves processes for the production of crystals essential for microelectronics, communication technologies, lasers and energy producing and energy saving technology. A deliberately added impurity is called an additive and in different industries these affect the process of crystal growth. Thus, understanding of interactions between additives and the crystallizing phases is important in different processes found in the lab, nature and in various industries. This book presents a generalized description of the mechanisms of action of additives during nucleation, growth and aggregation of crystals during crystallization and has received endorsement from the President of the International Organization for Crystal Growth. It is the first text devoted to the role of additives in different crystallization processes encountered in the lab, nature and in industries as diverse as pharmaceuticals, food and biofuels. A unique highlight of the book are chapters on the effect of additives on crystal growth processes, since the phenomena discussed is an issue of debate between researchers