Metal-Organic Frameworks with Heterogeneous Structures

Owing to the extensive interest in construction of functional metal organic frameworks (FMOFs), this book discusses the roles of functional groups on the structure and application of metal organic frameworks (MOFs). The contents of the book are classified based on the structural and chemical properties of organic functions, in order to make readers able to compare the different effects of each function on the structure and application of the MOFs. In each chapter, the chemical properties of applied functional groups are gathered to give deeper insight into the roles of organic functions in the structure and application of MOFs. In the function-application properties, the authors discuss how a functional group can dominate the host-guest chemistry of the MOFs and how this host-guest chemistry can expand the effectiveness and efficiency of the material in different fields of applications. Finally, function-structure properties are discussed. In function-application properties, it is discussed how a functional group can affect the topology, porosity, flexibility and stability of the framework. The features of this subject are novel and are presented for the first time.

Focusing on applications in separation, adsorption and catalysis, this handbook underlines the importance of this hot and exciting topic. It provides an excellent insight into the synthesis and modification of MOFs, their synthesis on an industrial scale, their use as CO2 and chemical warfare adsorbers, and the role of defects in catalysis. In addition, the authors treat such new aspects as biocatalysis and applications in photocatalysis and optoelectronic devices.

Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.

An international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: – Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future – Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification – Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks – Separation and purification of gases by MOFs – Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption – Manufacture of MOF thin films on structured supports for separation and catalysis – Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications – Separation of xylene isomers – Metal-Organic Frameworks as Catalysts for Organic Reactions – Biomedical applications of Metal Organic Frameworks – Metal Organic Frameworks for Biomedical Imaging – Luminescent Metal-Organic Frameworks – Deposition of thin films for sensor applications – Industrial MOF Synthesis – MOF shaping and immobilisation A must-have for every scientist in the field.

Organic Structures from Spectra, Fourth Edition consists of a carefully selected set of over 300 structural problems involving the use of all the major spectroscopic techniques. The problems are graded to develop and consolidate the student’s understanding of Organic Spectroscopy, with the accompanying text outlining the basic theoretical aspects of major spectroscopic techniques at a level sufficient to tackle the problems. Specific changes for the new edition will include A significantly expanded section on 2D NMR spectroscopy focusing on COSY, NOESY and CH-Correlation Incorporating new material into some tables to provide extra characteristic data for various classes of compounds Additional basic information on how to solve spectroscopic problems Providing new problems within the area of 10 2D NMR spectroscopy More problems at the ‘simpler’ end of the range As with previous editions, this book combines basic theory, practical advice and sensible approaches to solving spectra problems. It will therefore continue to prove invaluable to students studying organic spectroscopy across a range of disciplines.

A comprehensive introduction to the concepts of joining technologies for hybrid structures This book introduces the concepts of joining technology for polymer-metal hybrid structures by addressing current and new joining methods. This is achieved by using a balanced approach focusing on the scientific features (structural, physical, chemical, and metallurgical/polymer science phenomena) and engineering properties (mechanical performance, design, applications, etc.) of the currently available and new joining processes. It covers such topics as mechanical fastening, adhesive bonding, advanced joining methods, and statistical analysis in joining technology. Joining of Polymer-Metal Hybrid Structures: Principles and Applications is structured by joining principles, in adhesion-based, mechanical fastened, and direct-assembly methods. The book discusses such recent technologies as friction riveting, friction spot joining and ultrasonic joining. This is used for applications where the original base material characteristics must remain unchanged. Additional sections cover the main principles of statistical analysis in joining technology (illustrated with examples from the field of polymer-metal joining). Joining methods discussed include mechanical fastening (bolting, screwing, riveting, hinges, and fits of polymers and composites), adhesive bonding, and other advanced joining methods (friction staking, laser welding, induction welding, etc.). Provides a combined engineering and scientific approach used to describe principles, properties, and applications of polymer-metal hybrid joints Describes the current developments in design of experiments and statistical analysis in joining technology with emphasis on joining of polymer-metal hybrid structures Covers recent innovations in joining technology of polymer-metal hybrid joints including friction riveting, friction spot joining, friction staking, and ultrasonic joining Principles illustrated by pictures, 3D-schemes, charts, and drawings using examples from the field of polymer-metal joining Joining of Polymer-Metal Hybrid Structures: Principles and Applications will appeal to chemical, polymer, materials, metallurgical, composites, mechanical, process, product, and welding engineers, scientists and students, technicians, and joining process professionals.

Design and Analysis of Composite Structures enables graduate students and engineers to generate meaningful and robust designs of complex composite structures. Combining analysis and design methods for structural components, the book begins with simple topics such as skins and stiffeners and progresses through to entire components of fuselages and wings. Starting with basic mathematical derivation followed by simplifications used in real-world design, Design and Analysis of Composite Structures presents the level of accuracy and range of applicability of each method. Examples taken from actual applications are worked out in detail to show how the concepts are applied, solving the same design problem with different methods based on different drivers (e.g. cost or weight) to show how the final configuration changes as the requirements and approach change. Provides a toolkit of analysis and design methods to most situations encountered in practice, as well as analytical frameworks and the means to solving them for tackling less frequent problems. Presents solutions applicable to optimization schemes without having to run finite element models at each iteration, speeding up the design process and allowing examination of several more alternatives than traditional approaches. Includes guidelines showing how decisions based on manufacturing considerations affect weight and how weight optimization may adversely affect the cost. Accompanied by a website at www.wiley.com/go/kassapoglou hosting lecture slides and solutions to the exercises for instructors.