Reactive Intermediates. MS Investigations in Solution

Examines the latest applications of photochemistry to generate important intermediates Presenting the latest breakthroughs in the field of organic photochemistry, this book offers tested and proven photochemical approaches to synthesis, creating promising new possibilities and applications for photochemical reactions. It focuses on photoreactions involving an intermediate where mechanistic aspects control the course of the reaction and its synthetic value. Readers will discover new insights into the mechanisms and nature of photo-produced reactive intermediates for organic synthesis as well as the methods to generate them. Moreover, by focusing on highly efficient techniques for producing such species, the authors enable researchers to design and perform photoreactions within the framework of green, sustainable chemistry. Photochemically-Generated Intermediates in Synthesis begins with a discussion of the principles and practice of photo-generated intermediates. Next, the book explores: Photogeneration of carbon-centered radicals Photogeneration of heteroatom-centered radicals Photogeneration of biradicals and radical pairs Photochemical generation of radical ions Photogeneration of carbocations and carbanions Photogeneration of carbenes and nitrenes The book's final chapter is dedicated to the photochemical manipulation of intermediates. Each chapter includes key kinetic data for typical intermediates as well as detailed case examples, giving readers all the tools needed to perform their own photochemical reactions. Comparisons to non-photochemical methods are offered whenever possible. Photochemically-Generated Intermediates in Synthesis sets the stage for greater collaboration among photochemists and synthetic organic chemists, enabling these two research communities to fully leverage photochemistry in order to generate key intermediates needed for a broad range of synthetic reactions in organic chemistry.

Describes the basics of ROS metabolism in plants and examines the broad range of ROS signaling mechanisms New discoveries about the effects of reactive oxygen species (ROS) on plants have turned ROS from being considered a bane into a boon, because their roles have been discovered in many plant developmental processes as signaling molecules. This comprehensive book teaches about the role of ROS metabolism in plants and how they affect various developmental processes. It also discusses in detail the advancements made in understanding the ROS signaling. Reactive Oxygen Species in Plants: Boon Or Bane – Revisiting the Role of ROS begins by presenting the basic introduction to ROS and deciphers the detailed knowledge in ROS research. It then examines the broad range of ROS signaling mechanisms as well as how they may be beneficial for plants and human beings. This book also describes both the bane and boon aspects of ROS with their impact on plants, and how the recent revelations have compelled us to rethink ROS turning from stressors to plant regulators. ● Compiles, for the first time, the wholesome knowledge in ROS research and their cellular signaling ● Includes new discoveries and in-depth discussions about the advancements made in the field ● Discusses reactive oxygen species which are involved in a broad range of biological processes Reactive Oxygen Species in Plants: Boon Or Bane – Revisiting the Role of ROS will help scientists to utilize the functions of ROS signaling for plants and also enable readers to gain a deeper knowledge of ROS research and signaling. It is highly recommended for researchers, scientists, and academicians in plant science as well for advanced undergraduate and postgraduate students.

The vast majority of modern criminal investigations involve some element of digital evidence, from mobile phones, computers, CCTV and other devices. Digital Forensics: Digital Evidence in Criminal Investigations provides the reader with a better understanding of how digital evidence complements “traditional” scientific evidence and examines how it can be used more effectively and efficiently in a range of investigations. Taking a new approach to the topic, this book presents digital evidence as an adjunct to other types of evidence and discusses how it can be deployed effectively in support of investigations. The book provides investigators/SSMs/other managers with sufficient contextual and technical information to be able to make more effective use of digital evidence sources in support of a range of investigations. In particular, it considers the roles played by digital devices in society and hence in criminal activities. From this, it examines the role and nature of evidential data which may be recoverable from a range of devices, considering issues relating to reliability and usefulness of those data. Includes worked case examples, test questions and review quizzes to enhance student understanding Solutions provided in an accompanying website Includes numerous case studies throughout to highlight how digital evidence is handled at the crime scene and what can happen when procedures are carried out incorrectly Considers digital evidence in a broader context alongside other scientific evidence Discusses the role of digital devices in criminal activities and provides methods for the evaluation and prioritizing of evidence sources Includes discussion of the issues surrounding modern digital evidence examinations, for example; volume of material and its complexity Clear overview of all types of digital evidence Digital Forensics: Digital Evidence in Criminal Investigations is an invaluable text for undergraduate students taking either general forensic science courses where digital forensics may be a module or a dedicated computer/digital forensics degree course. The book is also a useful overview of the subject for postgraduate students and forensic practitioners.

Long-awaited on the importance of halogen bonding in solution, demonstrating the specific advantages in various fields – from synthesis and catalysis to biochemistry and electrochemistry! Halogen bonding (XB) describes the interaction between an electron donor and the electrophilic region of a halogen atom. Its applicability for molecular recognition processes long remained unappreciated and has mostly been studied in solid state until recently. As most physiological processes and chemical reactions take place in solution, investigations in solutions are of highest relevance for its use in organic synthesis and catalysis, pharmaceutical chemistry and drug design, electrochemistry, as well as material synthesis. Halogen Bonding in Solution gives a concise overview of halogen bond interactions in solution. It discusses the history and electronic origin of halogen bonding and summarizes all relevant examples of its application in organocatalysis. It describes the use of molecular iodine in catalysis and industrial applications, as well as recent developments in anion transport and binding. Hot topic: Halogen bonding is an important interaction between molecules or within a molecule. The field has developed considerably in recent years, with numerous different approaches and applications having been published. Unique: There are several books on halogen bonding in solid state available, but this will be the first one focused on halogen bonding in solution. Multi-disciplinary: Summarizes the history and nature of halogen bonding in solution as well as applications in catalysis, anion recognition, biochemistry, and electrochemistry. Aimed at facilitating exciting future developments in the field, Halogen Bonding in Solution is a valuable source of information for researchers and professionals working in the field of supramolecular chemistry, catalysis, biochemistry, drug design, and electrochemistry.

This unique text discusses the solution self-assembly of block copolymers and covers all aspects from basic physical chemistry to applications in soft nanotechnology. Recent advances have enabled the preparation of new materials with novel self-assembling structures, functionality and responsiveness and there have also been concomitant advances in theory and modelling. The present text covers the principles of self-assembly in both dilute and concentrated solution, for example micellization and mesophase formation, etc., in chapters 2 and 3 respectively. Chapter 4 covers polyelectrolyte block copolymers – these materials are attracting significant attention from researchers and a solid basis for understanding their physical chemistry is emerging, and this is discussed. The next chapter discusses adsorption of block copolymers from solution at liquid and solid interfaces. The concluding chapter presents a discussion of selected applications, focussing on several important new concepts. The book is aimed at researchers in polymer science as well as industrial scientists involved in the polymer and coatings industries. It will also be of interest to scientists working in soft matter self-assembly and self-organizing polymers.

In a reactive distillation column, both the chemical conversion and the distillative separation of the product mixture are carried out simultaneously. Through this integrative strategy, chemical equilibrium limitations can be overcome, higher selectivities can be achieved and heat of reaction can be directly used for distillation. Increased process efficiency and reduction of investments and operational costs are the direct results of this approach. Highly renowned international experts from both industry and academia review the state-of-the-art and the future directions in application, design, analysis and control of Reactive Distillation processes. Part I surveys various industrial applications and covers both established large scale processes as well as new chemical reaction schemes with high future potential. Part II provides the vital details for analysis of reactive phase equilibria, and discusses the importance of chemical reaction kinetics, while Part III focuses on identifying feasible column configurations and designing their internal structure. Analysis and control of the complex dynamic and steady-state behavior of reactive distillation processes are described in Part IV. Reactive Distillation – a very promising alternative to conventional reaction-distillation flow schemes.

Das Standardwerk zu Internal Investigations f?hrt die allgemeinen rechtlichen Grundlagen und Anforderungen an unternehmensinterne Ermittlungen mit praxiserprobten Darstellungen der f?r Wirtschaftsunternehmen aller Branchen relevanten Fachgebiete zusammen. Zahlreiche umfassende gesetzliche ?nderungen, wie z.B. bei der Selbstanzeige, im WpHG oder im Korruptionsstrafrecht, waren einzuarbeiten. Erweitert wurde das Handbuch um Beitr?ge zur Personen?berwachung und den kommunikativen Herausforderungen bei einer Internal Investigations sowie presserechtlichen Vorgaben f?r Compliance-Krisen. Im ersten Teil werden s?mtliche grundlegenden Querschnittsthemen wie gesellschafts- und arbeitsrechtliche Grundlagen, Anforderungen an Art und Umfang einer Internal Investigation – auch grenz?berschreitend – aufbereitet. Einen f?r den Praktiker besonderen Reiz haben Kapitel ?ber die Planung und Organisation der Investigation, die Dokumentenanalyse, die Datenaufbereitung sowie die Mitarbeiterbefragung. Standards setzt das Handbuch auch beim Datenschutz, bei Kronzeugen- und Amnestieprogrammen sowie der Reorganisation eines von der Investigation betroffenen Unternehmens. Darauf aufbauend umfasst der zweite Teil ausf?hrliche Kompendien f?r themenspezifische Aufkl?rungsma?nahmen einschlie?lich materiell-rechtlicher Grundlagen sowie prozessualer Besonderheiten u.a. zu den Themen: Korruption im Vertrieb, steuerrechtliche Verfehlungen, Verm?genssch?digung des Unternehmens durch Mitarbeiter, kartellrechtliche Verfehlungen, Geheimnisverrat und illegaler Know-how-Transfer, Unf?lle und Katastrophen, Kapitalmarktstraftaten, Au?enwirtschafts- und Zolldelikte.

This first comprehensive overview of reactive extrusion technology for over a decade combines the views of contributors from both academia and industry who share their experiences and highlight possible applications and markets. They also provide updated information on the underlying chemical and physical concepts, summarizing recent developments in terms of the material and machinery used. As a result, readers will find here a compilation of potential applications for reactive extrusion to access new and cost-effective polymeric materials, while using existing compounding machines.

Explores new applications emerging from our latest understanding of proteins in solution and at interfaces Proteins in solution and at interfaces increasingly serve as the starting point for exciting new applications, from biomimetic materials to nanoparticle patterning. This book surveys the state of the science in the field, offering investigators a current understanding of the characteristics of proteins in solution and at interfaces as well as the techniques used to study these characteristics. Moreover, the authors explore many of the new and emerging applications that have resulted from the most recent studies. Topics include protein and protein aggregate structure; computational and experimental techniques to study protein structure, aggregation, and adsorption; proteins in non-standard conditions; and applications in biotechnology. Proteins in Solution and at Interfaces is divided into two parts: Part One introduces concepts as well as theoretical and experimental techniques that are used to study protein systems, including X-ray crystallography, nuclear magnetic resonance, small angle scattering, and spectroscopic methods Part Two examines current and emerging applications, including nanomaterials, natural fibrous proteins, and biomolecular thermodynamics The book's twenty-three chapters have been contributed by leading experts in the field. These contributions are based on a thorough review of the latest peer-reviewed findings as well as the authors' own research experience. Chapters begin with a discussion of core concepts and then gradually build in complexity, concluding with a forecast of future developments. Readers will not only gain a current understanding of proteins in solution and at interfaces, but also will discover how theoretical and technical developments in the field can be translated into new applications in material design, genetic engineering, personalized medicine, drug delivery, biosensors, and biotechnology.

In this provocatively compelling new book, Michael Luntley offers a revolutionary reading of the opening section of Wittgenstein’s Philosophical Investigations Critically engages with the most recent exegetical literature on Wittgenstein and other state-of-the-art philosophical work Encourages the re-incorporation of Wittgenstein studies into the mainstream philosophical conversation Has profound consequences for how we go on to read the rest of Wittgenstein’s major work Makes a significant contribution not only to the literature on Wittgenstein, but also to studies in philosophy of language