Terpyridine-based Materials

Over the past two decades, the rapid development of nanochemistry and nanotechnology has allowed the synthesis of various materials and oxides in the form of nanopowders making it possible to produce new energetic compositions and nanomaterials. This book has a bottom-up structure, from nanomaterials synthesis to the application fields. Starting from aluminum nanoparticles synthesis for fuel application, it proposes a detailed state-of-the art of the different methods of preparation of aluminum-based reactive nanomaterials. It describes the techniques developed for their characterization and, when available, a description of the fundamental mechanisms responsible for their ignition and combustion. This book also presents the possibilities and limitations of different energetic nanomaterials and related structures as well as the analysis of their chemical and thermal properties. The whole is rounded off with a look at the performances of reactive materials in terms of heat of reaction and reactivity mainly characterized as the self-sustained combustion velocity. The book ends up with a description of current reactive nanomaterials applications underlying the promising integration of aluminum-based reactive nanomaterial into micro electromechanical systems.

It is well known that solid carbons can be found in various guises with different forms of bulk phases (graphites, diamonds and carbynes) as well as more molecular forms (fullerenes,nanotubes and graphenes) resulting from recent discoveries. The cause of this rich polymorphism is analyzed in the first part of this book (chapters 1-5) with the propensity of carbon atoms for forming different types of homopolar chemical bonds associated with variable coordination numbers. Precursor organic molecules and parent compounds are also described to establish specific links with this rich polymorphism. Then in a second part (chapters 6-10) a comparative review of the main classes of bulk physical properties is presented. This approach emphasizes in particular the electronic behavior of (pi) polyaromatic systems organized in plane and curved atomic sheets. Finally in a third part (chapters 11-15) the surface and interface characteristics are introduced together with the texture and morphology of these multiscale carbon materials. An overview of the main field of applications is related showing the large use and interest for these solids.

This exciting new book details all aspects of a major class of pyrolants and elucidates the progress that has been made in the field, covering both the chemistry and applications of these coompounds. Written by a pre-eminent authority on the subject from the NATO Munitions Safety Information Analysis Center (MSIAC), it begins with a historical overview of the development of these materials, followed by a thorough discussion of their ignition, combustion and radiative properties. The next section explores the multiple facets of their military and civilian applications, as well as industrial synthetic techniques. The critical importance of the associated hazards, namely sensitivity, stability and aging, are discussed in detail, and the book is rounded off by an examination of the future of this vital and expanding field. The result is a complete guide to the chemistry, manufacture, applications and required safety precautions of pyrolants for both the military and chemical industries. From the preface: «… This book fills a void in the collection of pyrotechnic literature… it will make an excellent reference book that all researchers of pyrolants and energetics must have…» Dr. Bernard E. Douda, Dr. Sara Pliskin, NAVSEA Crane, IN, USA

The first book to didactically illustrate this particular, prominent class of supramolecular building-blocks covers topics ranging from terpyridine syntheses, via their chemistry and properties, supramolecular structures, and multinuclear metal complexes, right up to functionalized polymers, 3D-architectures, and surfaces. Invaluable for students and lecturers in chemistry and biochemistry, materials scientists, as well as polymer, complex and physicochemists.

High-Performance Materials from Bio-based Feedstocks High-Performance Materials from Bio-based Feedstocks The latest advancements in the production, properties, and performance of bio-based feedstock materials In High-Performance Materials from Bio-based Feedstocks , an accomplished team of researchers delivers a comprehensive exploration of recent developments in the research, manufacture, and application of advanced materials from bio-based feedstocks. With coverage of bio-based polymers, the inorganic components of biomass, and the conversion of biomass to advanced materials, the book illustrates the research and commercial potential of new technologies in the area. Real-life applications in areas as diverse as medicine, construction, synthesis, energy storage, agriculture, packaging, and food are discussed in the context of the structural properties of the materials used. The authors offer deep insights into materials production, properties, and performance. Perfect for chemists, environmental scientists, engineers, and materials scientists, High-Performance Materials from Bio-based Feedstocks will also earn a place in the libraries of academics, industrial researchers, and graduate students with an interest in biomass conversion, green chemistry, and sustainability. A thorough introduction to the latest developments in advanced bio-based feedstock materials research Comprehensive explorations of a vast range of real-world applications, from tissue scaffolds and drug delivery to batteries, sorbents, and controlled release fertilizers Practical discussions of the organic and inorganic components of biomass and the conversion of biomass to advanced materials In-depth examinations of the structural properties of commercially and academically significant biomass materials For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs

Electrochemical capacitors are electrochemical energy storage devices able to quickly deliver or store large quantities of energy. They have stimulated numerous innovations throughout the last 20 years and are now implemented in many fields. Supercapacitors Based on Carbon or Pseudocapacitive Materials provides the scientific basis for a better understanding of the characteristics and performance of electrochemical capacitors based on electrochemical double layer electrodes or pseudocapacitive materials, as well as providing information on the design and conception of new devices such as lithium-ion capacitors. This book details the various applications of supercapacitors, ranging from power electronics and stationary use, to transportation (hybrid vehicles, trams, planes, etc.). They are increasingly used in the automotive sector, especially as part of stop/start systems that have allowed for energy recovery through braking and reduced fuel consumption.

Using plant material as raw materials for construction is a relatively recent and original topic of research. This book presents an overview of the current knowledge on the material properties and environmental impact of construction materials made from plant particles, which are renewable, recyclable and easily available. It focuses on particles and as well on fibers issued from hemp plant, as well as discussing hemp concretes. The book begins by setting the environmental, economic and social context of agro-concretes, before discussing the nature of plant-based aggregates and binders. The formulation, implementation and mechanical behavior of such building materials are the subject of the following chapters. The focus is then put upon the hygrothermal behavior and acoustical properties of hempcrete, followed by the use of plant-based concretes in structures. The book concludes with the study of life-cycle analysis (LCA) of the environmental characteristics of a banked hempcrete wall on a wooden skeleton. Contents 1. Environmental, Economic and Social Context of Agro-Concretes, Vincent Nozahic and Sofiane Amziane. 2. Characterization of Plant-Based Aggregates. Vincent Picandet. 3. Binders, Gilles Escadeillas, Camille Magniont, Sofiane Amziane and Vincent Nozahic. 4. Formulation and Implementation, Christophe Lanos, Florence Collet, G?rard Lenain and Yves Hustache. 5. Mechanical Behavior, Laurent Arnaud, Sofiane Amziane, Vincent Nozahic and Etienne Gourlay. 6. Hygrothermal Behavior of Hempcrete, Laurent Arnaud, Driss Samri and ?tienne Gourlay. 7. Acoustical Properties of Hemp Concretes, Philippe Gl?, Emmanuel Gourdon and Laurent Arnaud. 8. Plant-Based Concretes in Structures: Structural Aspect – Addition of a Wooden Support to Absorb the Strain, Philippe Munoz and Didier Pipet. 9. Examination of the Environmental Characteristics of a Banked Hempcrete Wall on a Wooden Skeleton, by Lifecycle Analysis: Feedback on the LCA Experiment from 2005, Marie-Pierre Boutin and Cyril Flamin. About the Authors Sofiane Amziane is Professor and head of the Civil Engineering department at POLYTECH Clermont-Ferrand in France. He is also in charge of the research program dealing with bio-based building materials at Blaise Pascal University (Institut Pascal, Clermont Ferrand, France). He is the secretary of the RILEM Technical Committee 236-BBM dealing with bio-based building materials and the author or co-author of over one hundred papers in scientific journals such as Cement and Concrete Research, Composite Structures or Construction Building Materials as well as international conferences. Laurent Arnaud is a Bridges, Waters and Forestry Engineer (Ing?nieur des Ponts, Eaux et For?ts) and researcher at Joseph Fourier University in Grenoble, France. He is also Professor at ENTPE (Ecole Nationale des Travaux Publics de l’Etat). Trained in the field of mechanical engineering, his research has been directed toward the characterization and development of new materials for civil engineering and construction. He is head of the international committee at RILEM – BBM, as well as the author of more than one hundred publications, and holder of an international invention patent.

The number of ceramic materials with a perovskite type structure is large and of considerable technological importance due to their rich crystal chemistry and structure-property relationships. Applications include multilayer capacitators, piezoelectric transducers, PTC thermistors, electrooptical modulators, optical switches, dielectric resonators, thick film resistors, electronic sensors, electrorestrictive actuators, magnetic bubble memory devices, laser host materials, ferromagnetic materials, refractory electrodes, second harmonic generators, batteries, ceramic electrodes, thermoelectric devices, and high temperature superconductors. This volume contains papers on the research and development of new perovskite materials for various applications including doping of existing perovskite materials as well as processing for improved properties.

This book addresses the need for a comprehensive book on the design, synthesis, and characterization of synthetic carbohydrate-based polymeric materials along with their biological applications. The first two chapters cover the synthesis and self-assembly of glycopolymers and different techniques for creating these synthetic polymers. Subsequent chapters account for the preparation of block copolymers, branched glycopolymers, glycosurfaces, glycodendrimers, cationic glycopolymers, bioconjugates, glyconanoparticles and hydrogels. While these chapters comprehensively review the synthetic and characterization methods of those carbohydrate-based materials, their biological applications are discussed in detail.