Carbon-Centered Free Radicals and Radical Cations. Structure, Reactivity, and Dynamics

Comprehensive coverage of radical reactive intermediates in nucleic acid chemistry and biochemistry The Wiley Series on Reactive Intermediates in Chemistry and Biology investigates reactive intermediates from the broadest possible range of disciplines. The contributions in each volume offer readers fresh insights into the latest findings, emerging applications, and ongoing research in the field from a diverse perspective. The chemistry and biochemistry of reactive intermediates is central to organic chemistry and biochemistry, and underlies a significant portion of modern synthetic chemistry. Radical and Radical Ion Reactivity in Nucleic Acid Chemistry provides the only comprehensive review of the chemistry and biochemistry of nucleic acid radical intermediates. With contributions by world leaders in the field, the text covers a broad range of topics, including: A discussion of the relevant theory Ionization of DNA Nucleic acid sugar radicals Halopyrimidines Oxidative, reductive, and low energy electron transfer Electron affinity sensitizers Photochemical generative of reactive oxygen species Reactive nitrogen species Enediyne rearrangements Phenoxyl radicals A unique compilation on the cutting edge of our understanding, Radical and Radical Ion Reactivity in Nucleic Acid Chemistry provides an unparalleled resource to student and professional researchers in such fields as organic chemistry, biochemistry, molecular biology, and physical chemistry, as well as the industries associated with these disciplines.

This volume concentrates on catalysis in biochemical environments, giving new perspectives to previous research, current developments and future directions. Topics range from micelles performing catalytic reactions, active sites on heme proteins and synthetic control of oligonucleotide structures to design of proteins, self-assembling structures and self-replicating molecules. A comprehensive survey of the literature on supramolecular chemistry for 1993-94 is also included.

The Novartis Foundation Series is a popular collection of the proceedings from Novartis Foundation Symposia, in which groups of leading scientists from a range of topics across biology, chemistry and medicine assembled to present papers and discuss results. The Novartis Foundation, originally known as the Ciba Foundation, is well known to scientists and clinicians around the world.

A first on ultrafast phenomena in carbon nanostructures like graphene, the most promising candidate for revolutionizing information technology and communication The book introduces the reader into the ultrafast nanoworld of graphene and carbon nanotubes, including their microscopic tracks and unique optical finger prints. The author reviews the recent progress in this field by combining theoretical and experimental achievements. He offers a clear theoretical foundation by presenting transparently derived equations. Recent experimental breakthroughs are reviewed. By combining both theory and experiment as well as main results and detailed theoretical derivations, the book turns into an inevitable source for a wider audience from graduate students to researchers in physics, materials science, and electrical engineering who work on optoelectronic devices, renewable energies, or in the semiconductor industry.

The Amazon Basin contains the largest and most diverse tropical rainforest in the world. Besides the Andes and the Atlantic Ocean, the rainforest is bounded to the north by the Guiana crystalline shield and to the south by the Brazilian crystalline shield, marked at their edges by cataracts in the rivers and often dominated by grasslands. This book is motivated not just by the Amazon's scientific interest but also by its role in many ecosystem functions critical to life on Earth. These ecosystems are characterized both by their complexity and their interactive, higher-order linkages among both abiotic and biotic components. Within Amazonia, the Western Amazon (west of 65° latitude) is the most pristine and, perhaps, the most complex within the Amazon Basin. This Western Amazon may be broadly divided into non-flooded forests (e.g. terra firme, white sand, palm) and forests flooded with white water (generally referred to as v?rzea) and with black water (generally referred to as igap?). Here, for the first time, is a book devoted entirely to Western Amazonia, containing chapters by scientists at the forefront of their own areas of expertise. It should be a valuable resource for all future researchers and scholars who venture into Western Amazonia, as it continues to be one of the most beautiful, mysterious, remote and important ecosystems on Earth.

A new title in the Manchester Physics Series, this introductory text emphasises physical principles behind classical mechanics and relativity. It assumes little in the way of prior knowledge, introducing relevant mathematics and carefully developing it within a physics context. Designed to provide a logical development of the subject, the book is divided into four sections, introductory material on dynamics, and special relativity, which is then followed by more advanced coverage of dynamics and special relativity. Each chapter includes problems ranging in difficulty from simple to challenging with solutions for solving problems. Includes solutions for solving problems Numerous worked examples included throughout the book Mathematics is carefully explained and developed within a physics environment Sensitive to topics that can appear daunting or confusing

Provides the basics of spacecraft orbital dynamics plus attitude dynamics and control, using vectrix notation Spacecraft Dynamics and Control: An Introduction presents the fundamentals of classical control in the context of spacecraft attitude control. This approach is particularly beneficial for the training of students in both of the subjects of classical control as well as its application to spacecraft attitude control. By using a physical system (a spacecraft) that the reader can visualize (rather than arbitrary transfer functions), it is easier to grasp the motivation for why topics in control theory are important, as well as the theory behind them. The entire treatment of both orbital and attitude dynamics makes use of vectrix notation, which is a tool that allows the user to write down any vector equation of motion without consideration of a reference frame. This is particularly suited to the treatment of multiple reference frames. Vectrix notation also makes a very clear distinction between a physical vector and its coordinate representation in a reference frame. This is very important in spacecraft dynamics and control problems, where often multiple coordinate representations are used (in different reference frames) for the same physical vector. Provides an accessible, practical aid for teaching and self-study with a layout enabling a fundamental understanding of the subject Fills a gap in the existing literature by providing an analytical toolbox offering the reader a lasting, rigorous methodology for approaching vector mechanics, a key element vital to new graduates and practicing engineers alike Delivers an outstanding resource for aerospace engineering students, and all those involved in the technical aspects of design and engineering in the space sector Contains numerous illustrations to accompany the written text. Problems are included to apply and extend the material in each chapter Essential reading for graduate level aerospace engineering students, aerospace professionals, researchers and engineers.

One of the major challenges facing the world today is the interaction between demographic change and development. Demographic Dynamics and Development reviews the dominant demographic theory, demographic transition, and then presents a thorough investigation covering aging, fertility, contraception, nuptiality, mortality and migration, which are all aspects that drive these changes. Each chapter combines the latest empirical data with theoretical reflections on the implications for development.

This book thus offers an overview of worldwide demographic data, studied with a view towards development. In doing so, it provides researchers and specialists with clear information through in-depth case studies, focusing on a country, a region or a particularly important scientific sub-theme.

A guide to the latest developments in grid dynamics and control and highlights the role of transmission and distribution grids Dynamics and Control of Electric Transmission and Microgrids offers a concise and comprehensive review of the most recent developments and research in grid dynamics and control. In addition, the authors present a new style of presentation that highlights the role of transmission and distribution grids that ensure the reliability and quality of electric power supply. The authors – noted experts in the field – offer an introduction to the topic and explore the basic characteristics and operations of the grid. The text also reviews a wealth of vital topics such as FACTS and HVDC Converter controllers, the stability and security issues of the bulk power system, loads which can be viewed as negative generation, the power limits and energy availability when distributed storage is used and much more. This important resource: Puts the focus on the role of transmission and distribution grids that ensure the reliability and quality of electric power supply Includes modeling and control of wind and solar energy generation for secure energy transfer Presents timely coverage of on-line detection of loss of synchronism, wide area measurements and applications, wide-area feedback control systems for power swing damping and microgrids-operation and control Written for students of power system dynamics and control/electrical power industry professionals, Dynamics and Control of Electric Transmission and Microgrids is a comprehensive guide to the recent developments in grid dynamics and control and highlights the role of transmission and distribution grids that ensure the reliability and quality of electric power supply.

A comprehensive overview of integrated vehicle system dynamics exploring the fundamentals and new and emerging developments This book provides a comprehensive coverage of vehicle system dynamics and control, particularly in the area of integrated vehicle dynamics control. The book consists of two parts, (1) development of individual vehicle system dynamic model and control methodology; and (2) development of integrated vehicle dynamic model and control methodology. The first part focuses on investigating vehicle system dynamics and control according to the three directions of vehicle motions, including longitudinal, vertical, and lateral. Corresponding individual control systems, e.g. Anti-lock Brake System (ABS), Active Suspension, Electric Power Steering System (EPS), are introduced and developed respectively. Particular attention is paid in the second part of the book to develop integrated vehicle dynamic control system. Integrated vehicle dynamics control system is an advanced system that coordinates all the chassis control systems and components to improve the overall vehicle performance including safety, comfort, and economy. Integrated vehicle dynamics control has been an important research topic in the area of vehicle dynamics and control over the past two decades. The research topic on integrated vehicle dynamics control is investigated comprehensively and intensively in the book through both theoretical analysis and experimental study. In this part, two types of control architectures, i.e. centralized and multi-layer, have been developed and compared to demonstrate their advantages and disadvantages. Integrated vehicle dynamics control is a hot topic in automotive research; this is one of the few books to address both theory and practice of integrated systems Comprehensively explores the research area of integrated vehicle dynamics and control through both theoretical analysis and experimental study Addresses a full range of vehicle system topics including tyre dynamics, chassis systems, control architecture, 4 wheel steering system and design of control systems using Linear Matrix Inequality (LMI) Method