Carbon Nanotubes and Related Structures. Synthesis, Characterization, Functionalization, and Applications

Since the publication of the successful first edition of the book in 2010, the field has matured and a large number of advancements have been made to the science of polymer nanotube nanocomposites (PNT) in terms of synthesis, filler surface modification, as well as properties. Moreover, a number of commercial applications have been realized. The aim of this second volume of the book is, thus, to update the information presented in the first volume as well as to incorporate the recent research and industrial developments. This edited volume brings together contributions from a variety of senior scientists in the field of polymer nanotube composites technology to shed light on the recent advances in these commercially important areas of polymer technology. The book provides the following features: Reviews the various synthesis techniques, properties and applications of the polymer nanocomposite systems Describes the functionalization strategies for single walled nanotubes in order to achieve their nanoscale dispersion in epoxy matrices Provides insights into the multiscale modeling of the properties of PNT Provides perspectives on the electron microscopy characterization of PNT Presents an overview of the different methodologies to achieve micro-patterning of PNT Describes the recent progress on hybridization modifications of CNTs with carbon nanomaterials and their further applications in polymer nanocomposites Provides details on the foams generates with PNT Provides information on synthesis and properties of polycarbonate nanocomposite. Describes the advanced microscopy techniques for understanding of the polymer/nanotube composite interfaces and properties.

Carbon nanotubes are exceptionally interesting from a fundamental research point of view. Many concepts of one-dimensional physics have been verified experimentally such as electron and phonon confinement or the one-dimensional singularities in the density of states; other 1D signatures are still under debate, such as Luttinger-liquid behavior. Carbon nanotubes are chemically stable, mechanically very strong, and conduct electricity. For this reason, they open up new perspectives for various applications, such as nano-transistors in circuits, field-emission displays, artificial muscles, or added reinforcements in alloys. This text is an introduction to the physical concepts needed for investigating carbon nanotubes and other one-dimensional solid-state systems. Written for a wide scientific readership, each chapter consists of an instructive approach to the topic and sustainable ideas for solutions. The former is generally comprehensible for physicists and chemists, while the latter enable the reader to work towards the state of the art in that area. The book gives for the first time a combined theoretical and experimental description of topics like luminescence of carbon nanotubes, Raman scattering, or transport measurements. The theoretical concepts discussed range from the tight-binding approximation, which can be followed by pencil and paper, to first-principles simulations. We emphasize a comprehensive theoretical and experimental understanding of carbon nanotubes including – general concepts for one-dimensional systems – an introduction to the symmetry of nanotubes – textbook models of nanotubes as narrow cylinders – a combination of ab-initio calculations and experiments – luminescence excitation spectroscopy linked to Raman spectroscopy – an introduction to the 1D-transport properties of nanotubes – effects of bundling on the electronic and vibrational properties and – resonance Raman scattering in nanotubes.

This book is the first of its kind to reflect upon the intense and rapidly growing interest in open geodesic polyaromatic molecules, specifically focusing on their synthesis and reactivity in metal binding reactions. The book broadly covers all aspects related to the fullerene fragment chemistry: current synthetic techniques, description of the available members of this new family (which has grown to more than two dozens members, with none being available commercially), molecular geometry and trends in the solid state packing, as well as extensions into physical properties and new buckybowl-based molecules and materials. It covers fundamental research related to a new class of hydrocarbons, namely open geodesic polyarenes that map onto the surfaces of fullerenes (and referred to as fullerene fragments or buckybowls.

Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications – from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.

A first on ultrafast phenomena in carbon nanostructures like graphene, the most promising candidate for revolutionizing information technology and communication The book introduces the reader into the ultrafast nanoworld of graphene and carbon nanotubes, including their microscopic tracks and unique optical finger prints. The author reviews the recent progress in this field by combining theoretical and experimental achievements. He offers a clear theoretical foundation by presenting transparently derived equations. Recent experimental breakthroughs are reviewed. By combining both theory and experiment as well as main results and detailed theoretical derivations, the book turns into an inevitable source for a wider audience from graduate students to researchers in physics, materials science, and electrical engineering who work on optoelectronic devices, renewable energies, or in the semiconductor industry.

The main properties that make carbon nanotubes (CNTs) a promising technology for many future applications are: extremely high strength, low mass density, linear elastic behavior, almost perfect geometrical structure, and nanometer scale structure. Also, CNTs can conduct electricity better than copper and transmit heat better than diamonds. Therefore, they are bound to find a wide, and possibly revolutionary use in all fields of engineering. The interest in CNTs and their potential use in a wide range of commercial applications; such as nanoelectronics, quantum wire interconnects, field emission devices, composites, chemical sensors, biosensors, detectors, etc.; have rapidly increased in the last two decades. However, the performance of any CNT-based nanostructure is dependent on the mechanical properties of constituent CNTs. Therefore, it is crucial to know the mechanical behavior of individual CNTs such as their vibration frequencies, buckling loads, and deformations under different loadings. This title is dedicated to the vibration, buckling and impact behavior of CNTs, along with theory for carbon nanosensors, like the Bubnov-Galerkin and the Petrov-Galerkin methods, the Bresse-Timoshenko and the Donnell shell theory.

Carbon dioxide sequestration is a technology that is being explored to curb the anthropogenic emission of CO2 into the atmosphere. Carbon dioxide has been implicated in the global climate change and reducing them is a potential solution. The injection of carbon dioxide for enhanced oil recovery (EOR) has the duel benefit of sequestering the CO2 and extending the life of some older fields. Sequestering CO2 and EOR have many shared elements that make them comparable. This volume presents some of the latest information on these processes covering physical properties, operations, design, reservoir engineering, and geochemistry for AGI and the related technologies.

This ready reference and handbook is unique in its focus on synthesis and the application of graphene and other carbon materials with an emphasis on chemistry aspects. To this extent, it deals with top-down and bottom-up approaches across the different length scales for graphene from polycyclic aromatic hydrocarbons to graphene nanoribbons and graphene sheets, as well as carbon materials from quantum dots, nanostructured particles, and fibers, right up to tubes, bulk structures, and much more besides. In so doing, it presents the best synthetic methods: pyrolysis, chemical vapor deposition, templating and surface-mediated synthesis, self-assembly, surface-grafting and modification. Edited by two excellent, experienced and highly renowned editors, both of whom are directors of Max Planck Institutes.

Electrostatic discharge (ESD) continues to impact semiconductor components and systems as technologies scale from micro- to nano-electronics. This book studies electrical overstress, ESD, and latchup from a whole-chip ESD design synthesis approach. It provides a clear insight into the integration of ESD protection networks from a generalist perspective, followed by examples in specific technologies, circuits, and chips. Uniquely both the semiconductor chip integration issues and floorplanning of ESD networks are covered from a ‘top-down' design approach. Look inside for extensive coverage on: integration of cores, power bussing, and signal pins in DRAM, SRAM, CMOS image processing chips, microprocessors, analog products, RF components and how the integration influences ESD design and integration architecturing of mixed voltage, mixed signal, to RF design for ESD analysis floorplanning for peripheral and core I/O designs, and the implications on ESD and latchup guard ring integration for both a ‘bottom-up' and ‘top-down' methodology addressing I/O guard rings, ESD guard rings, I/O to I/O, and I/O to core classification of ESD power clamps and ESD signal pin circuitry, and how to make the correct choice for a given semiconductor chip examples of ESD design for the state-of-the-art technologies discussed, including CMOS, BiCMOS, silicon on insulator (SOI), bipolar technology, high voltage CMOS (HVCMOS), RF CMOS, and smart power practical methods for the understanding of ESD circuit power distribution, ground rule development, internal bus distribution, current path analysis, quality metrics ESD: Design and Synthesis is a continuation of the author's series of books on ESD protection. It is an essential reference for: ESD, circuit, and semiconductor engineers; design synthesis team leaders; layout design, characterisation, floorplanning, test and reliability engineers; technicians; and groundrule and test site developers in the manufacturing and design of semiconductor chips. It is also useful for graduate and undergraduate students in electrical engineering, semiconductor sciences, and manufacturing sciences, and on courses involving the design of ESD devices, chips and systems. This book offers a useful insight into the issues that confront modern technology as we enter the nano-electronic era.