Chirality at the Nanoscale. Nanoparticles, Surfaces, Materials and More

The only standard reference in this exciting new field combines the physical, chemical and material science perspectives in a synergic way. This monograph traces the development of the preparative methods employed to create nanostructures, in addition to the experimental techniques used to characterize them, as well as some of the surprising physical effects. The chapters cover every category of material, from organic to coordination compounds, metals and composites, in zero, one, two and three dimensions. The book also reviews structural, chemical, optical, and other physical properties, finishing with a look at the future for chiral nanosystems.

A comprehensive introduction to the fundamental aspects of surface chirality, covering both chemical and physical consequences Written by a leading expert in the field, Chirality at Solid Surfaces offers an introduction to the concept of chirality at surfaces, starting from the foundation of chirality in isolated molecules and bulk systems. Fundamental properties such as surface energy and surface stress are then linked to a universal systematization of surface structure and symmetry. The author includes key examples of surface chemistry and physics, such as the interplay between adsorbate and substrate chirality, amplification of chirality, chiral catalysis, and the influence of surface chirality upon optical and magnetic phenomena. The book also explores the chirality apparent in the electronic structure of graphene, topological insulators and half-metallic materials. This important reference: Provides an introduction to the fundamental concept of chirality Contains discussions of the chemical and physical consequences of surface chirality, including magnetic, electronic and optical properties in addition to molecular properties Offers an account of the most current research needed to support growth in the field Written for surface scientists, professionals in the field, academics, and students, Chirality at Solid Surfaces is an essential resource that contains an overview of the fundamentals of surface chirality and reviews both the chemical and physical consequences.

Topics in Stereochemistry, Materials-Chirality provides comprehensive information on the stereochemistry of materials. Coverage includes the chirality of materials and the important role stereochemistry plays in the physical properties of polymers, liquid crystals, and other materials.

Derived from the highly acclaimed series Materials Science and Technology, this book provides in-depth coverage of STM, AFM, and related non-contact nanoscale probes along with detailed applications, such as the manipulation of atoms and clusters on a nanometer scale. The methods are described in terms of the physics and the technology of the methods and many high-quality images demonstrate the power of these techniques in the investigation of surfaces and the processes which occur on them. Topics include: Semiconductor Surfaces and Interfaces * Insulators * Layered Compounds * Charge Density Wave Systems * Superconductors * Electrochemisty at Liquid-Solid Interfaces * Biological Systems * Metrological Applications * Nanoscale Surface Forces * Nanotribology * Manipulation on the Nanoscale Materials scientists, surface scientists, electrochemists, as well as scientists working in catalysis and microelectronics will find this book an invaluable source of information

This book addresses the need for a comprehensive book on the design, synthesis, and characterization of synthetic carbohydrate-based polymeric materials along with their biological applications. The first two chapters cover the synthesis and self-assembly of glycopolymers and different techniques for creating these synthetic polymers. Subsequent chapters account for the preparation of block copolymers, branched glycopolymers, glycosurfaces, glycodendrimers, cationic glycopolymers, bioconjugates, glyconanoparticles and hydrogels. While these chapters comprehensively review the synthetic and characterization methods of those carbohydrate-based materials, their biological applications are discussed in detail.

A comprehensive and interdisciplinary resource filled with strategic insights, tools, and techniques for the design and construction of hybrid materials. Hybrid materials represent the best of material properties being combined for the development for materials with properties otherwise unavailable for application requirements. Novel Nanoscale Hybrid Materials is a comprehensive resource that contains contributions from a wide range of noted scientists from various fields, working on the hybridization of nanomolecules in order to generate new materials with superior properties. The book focuses on the new directions and developments in design and application of new materials, incorporating organic/inorganic polymers, biopolymers, and nanoarchitecture approaches. This book delves deeply into the complexities that arise when characteristics of a molecule change on the nanoscale, overriding the properties of the individual nanomolecules and generating new properties and capabilities altogether. The main topics cover hybrids of carbon nanotubes and metal nanoparticles, semiconductor polymer/biopolymer hybrids, metal biopolymer hybrids, bioorganic/inorganic hybrids, and much more. This important resource: Addresses a cutting-edge field within nanomaterials by presenting groundbreaking topics that address hybrid nanostructures Includes contributions from an interdisciplinary group of chemists, physicists, materials scientists, chemical and biomedical engineers Contains applications in a wide-range of fields—including biomedicine, energy, catalysis, green chemistry, graphene chemistry, and environmental science Offers expert commentaries that explore potential future avenues of future research trends Novel Nanoscale Hybrid Materials is an important resource for chemists, physicists, materials, chemical and biomedical engineers that offers the most recent developments and techniques in hybrid nanostructures.

An advanced level textbook covering geometric, chemical, and electronic structure of electronic materials, and their applications to devices based on semiconductor surfaces, metal-semiconductor interfaces, and semiconductor heterojunctions. Starting with the fundamentals of electrical measurements on semiconductor interfaces, it then describes the importance of controlling macroscopic electrical properties by atomic-scale techniques. Subsequent chapters present the wide range of surface and interface techniques available to characterize electronic, optical, chemical, and structural properties of electronic materials, including semiconductors, insulators, nanostructures, and organics. The essential physics and chemistry underlying each technique is described in sufficient depth with references to the most authoritative sources for more exhaustive discussions, while numerous examples are provided throughout to illustrate the applications of each technique. With its general reading lists, extensive citations to the text, and problem sets appended to all chapters, this is ideal for students of electrical engineering, physics and materials science. It equally serves as a reference for physicists, material science and electrical and electronic engineers involved in surface and interface science, semiconductor processing, and device modeling and design. This is a coproduction of Wiley and IEEE * Free solutions manual available for lecturers at www.wiley-vch.de/supplements/

As the ability to produce nanomaterials advances, it becomes more important to understand how the energy of the atoms in these materials is affected by their reduced dimensions. Written by an acclaimed author team, Kinetics in Nanoscale Materials is the first book to discuss simple but effective models of the systems and processes that have recently been discovered. The text, for researchers and graduate students, combines the novelty of nanoscale processes and systems with the transparency of mathematical models and generality of basic ideas relating to nanoscience and nanotechnology.

This book provides a comprehensive review of the state-of-the-art in the development of new and innovative materials, and of advanced modeling and characterization methods for nanoscale CMOS devices. Leading global industry bodies including the International Technology Roadmap for Semiconductors (ITRS) have created a forecast of performance improvements that will be delivered in the foreseeable future – in the form of a roadmap that will lead to a substantial enlargement in the number of materials, technologies and device architectures used in CMOS devices. This book addresses the field of materials development, which has been the subject of a major research drive aimed at finding new ways to enhance the performance of semiconductor technologies. It covers three areas that will each have a dramatic impact on the development of future CMOS devices: global and local strained and alternative materials for high speed channels on bulk substrate and insulator; very low access resistance; and various high dielectric constant gate stacks for power scaling. The book also provides information on the most appropriate modeling and simulation methods for electrical properties of advanced MOSFETs, including ballistic transport, gate leakage, atomistic simulation, and compact models for single and multi-gate devices, nanowire and carbon-based FETs. Finally, the book presents an in-depth investigation of the main nanocharacterization techniques that can be used for an accurate determination of transport parameters, interface defects, channel strain as well as RF properties, including capacitance-conductance, improved split C-V, magnetoresistance, charge pumping, low frequency noise, and Raman spectroscopy.

A comprehensive reference on nanoscale materials chemistry—now revised and updated. This extensive text provides twenty-two revised chapters on the preparations, applications, and characterization as well as the environmental and toxicological aspects of nanoscale materials, with an emphasis on the chemistry component. This Second Edition contains core topics including: New synthetic methods for nanomaterials Nanostructured solids Organized two- and three-dimensional nanocrystals Nanotubes, ribbons, and sheets Nanocatalysts, sorbents, and energy applications Unique physical properties of nanomaterials Photochemistry of nanomaterials Biological and environmental aspects of nanomaterials With input from top experts in the field, such as Bruce Dunn, Vicki Grassian, Warren Ford, and Chris Sorensen, among others, Nanoscale Materials in Chemistry presents a balanced survey of different topics in basic nanoparticle science, and includes helpful end-of-chapter questions and answers. Significantly expanded, the Second Edition remains a key text for understanding the fundamentals of nanoscale materials chemistry and a reliable resource for scientists and researchers.