Graphene

Graphene Materials: Fundamentals and Emerging Applications brings together innovative methodologies with research and development strategies to provide a detailed state-of-the-art overview of the processing, properties, and technology developments of graphene materials and their wide-ranging applications. The applications areas covered are biosensing, energy storage, environmental monitoring, and health. The book discusses the various methods that have been developed for the preparation and functionalization of single-layered graphene nanosheets. These form the essential building blocks for the bottom-up architecture of various graphene materials because they possess unique physico-chemical properties such as large surface areas, good conductivity and mechanical strength, high thermal stability and desirable flexibility. The electronic behavior in graphene, such as dirac fermions obtained due to the interaction with the ions of the lattice, has led to the discovery of novel miracles like Klein tunneling in carbon-based solid state systems and the so-called half-integer quantum Hall effect. The combination of these properties makes graphene a highly desirable material for applications. In particular, Graphene Materials: Fundamentals and Emerging Applications has chapters covering: • Graphene and related two-dimensional nanomaterials • Surface functionalization of graphene • Functional three-dimensional graphene networks • Covalent graphene-polymer nanocomposites • Magnesium matrix composites reinforced with graphene nanoplatelets • Graphene derivatives for energy storage • Graphene nanocomposite for high performance supercapacitors • Graphene nanocomposite-based bulk hetro-junction solar cells • Graphene bimetallic nanocatalysts foam for energy storage and biosensing • Graphene nanocomposites-based for electrochemical sensors • Graphene electrodes for health and environmental monitoring

What are the chemical aspects of graphene as a novel 2D material and how do they relate to the molecular structure? This book addresses these important questions from a theoretical and computational standpoint. Graphene Chemistry: Theoretical Perspectives presents recent exciting developments to correlate graphene’s properties and functions to its structure through state-of-the-art computational studies. This book focuses on the chemistry aspect of the structure-property relationship for many fascinating derivatives of graphene; various properties such as electronic structure, magnetism, and chemical reactivity, as well as potential applications in energy storage, catalysis, and nanoelectronics are covered. The book also includes two chapters with significant experimental portions, demonstrating how deep insights can be obtained by joint experimental and theoretical efforts. Topics covered include: Graphene ribbons: Edges, magnetism, preparation from unzipping, and electronic transport Nanographenes: Properties, reactivity, and synthesis Clar sextet rule in nanographene and graphene nanoribbons Porous graphene, nanomeshes, and graphene-based architecture and assemblies Doped graphene: Theory, synthesis, characterization and applications Mechanisms of graphene growth in chemical vapor deposition Surface adsorption and functionalization of graphene Conversion between graphene and graphene oxide Applications in gas separation, hydrogen storage, and catalysis Graphene Chemistry: Theoretical Perspectives provides a useful overview for computational and theoretical chemists who are active in this field and those who have not studied graphene before. It is also a valuable resource for experimentalist scientists working on graphene and related materials, who will benefit from many concepts and properties discussed here.

Due to its unique properties, graphene oxide has become one of the most studied materials of the last decade and a great variety of applications have been reported in areas such as sensors, catalysis and biomedical applications. This comprehensive volume systematically describes the fundamental aspects and applications of graphene oxide. The book is designed as an introduction to the topic, so each chapter begins with a discussion on fundamental concepts, then proceeds to review and summarize recent advances in the field. Divided into two parts, the first part covers fundamental aspects of graphene oxide and includes chapters on formation and chemical structure, characterization methods, reduction methods, rheology and optical properties of graphene oxide solutions. Part Two covers numerous graphene oxide applications including field effect transistors, transparent conductive films, sensors, energy harvesting and storage, membranes, composite materials, catalysis and biomedical applications. In each case the differences and advantages of graphene oxide over its non-oxidised counterpart are discussed. The book concludes with a chapter on the challenges of industrial-scale graphene oxide production. Graphene Oxide: Fundamentals and Applications is a valuable reference for academic researchers, and industry scientists interested in graphene oxide, graphene and other carbon materials.

Filling the gap between publications for industrial developers and academic researchers on graphene synthesis and its applications, this book presents the essential aspects for the successful upscaling of graphene production. After an introduction to graphene, its synthesis and characterization, the text covers a wide variety of graphene composites and compounds. The larger part of the book discusses various applications where graphene has been successfully integrated into technologies, including uses in the energy sector, oil and gas industry, biomedical areas, sensors and coatings. Finally, the book concludes with a summary and a look at the future of graphene technology, including a market review. With its focus on applications, this is equally useful for both academic and industrial users.

This first book dedicated to the topic provides an up-to-date account of the many opportunities graphene offers for robust, workable energy generation and storage devices. Following a brief overview of the fundamentals of graphene, including the main synthesis techniques, characterization methods and properties, the first part goes on to deal with graphene for energy storage applications, such as lithium-ion batteries, supercapacitors and hydrogen storage. The second part is concerned with graphene-based energy-generation devices, in particular conventional as well as microbial and enzymatic fuel cells, with chapters on graphene photovoltaics rounding off the book. Throughout, device architectures are not only discussed on a laboratory scale, but also ways for upscaling to an industrial level, including manufacturing processes and quality control. By bridging academic research and industrial development this is invaluable reading for materials scientists, physical chemists, electrochemists, solid state physicists, and those working in the electrotechnical industry.

Since its discovery in 2004, graphene has been a great sensation due to its unique structure and unusual properties, and it has only taken 6 years for a Noble Prize to be awarded for the field of graphene research. This monograph gives a well-balanced overview on all areas of scientific interest surrounding this fascinating nanocarbon. In one handy volume it offers comprehensive coverage of the topic, including chemical, materials science, nanoscience, physics, engineering, life science, and potential applications. Other graphene-like, inorganic layered materials are also discussed. Edited by two highly honored scientists, this is an invaluable companion for inorganic, organic, and physical chemists, materials scientists, and physicists. From the Contents: * Synthesis, Characterization, and Selected Properties of Graphene * Understanding Graphene via Raman Scattering * Physics of Quanta and Quantum Fields in Graphene * Graphene and Graphene-Oxide-Based Materials for Electrochemical Energy Systems * Heterogeneous Catalysis by Metal Nanoparticles supported on Graphene * Graphenes in Supramolecular Gels and in Biological Systems and many more

All set to become the standard reference on the topic, this book covers the most important procedures for chemical functionalization, making it an indispensable resource for all chemists, physicists, materials scientists and engineers entering or already working in the field. Expert authors share their knowledge on a wide range of different functional groups, including organic functional groups, hydrogen, halogen, nanoparticles and polymers.

Raman spectroscopy is the inelastic scattering of light by matter. Being highly sensitive to the physical and chemical properties of materials, as well as to environmental effects that change these properties, Raman spectroscopy is now evolving into one of the most important tools for nanoscience and nanotechnology. In contrast to usual microscopyrelated techniques, the advantages of using light for nanoscience relate to both experimental and fundamental aspects.

This ready reference and handbook is unique in its focus on synthesis and the application of graphene and other carbon materials with an emphasis on chemistry aspects. To this extent, it deals with top-down and bottom-up approaches across the different length scales for graphene from polycyclic aromatic hydrocarbons to graphene nanoribbons and graphene sheets, as well as carbon materials from quantum dots, nanostructured particles, and fibers, right up to tubes, bulk structures, and much more besides. In so doing, it presents the best synthetic methods: pyrolysis, chemical vapor deposition, templating and surface-mediated synthesis, self-assembly, surface-grafting and modification. Edited by two excellent, experienced and highly renowned editors, both of whom are directors of Max Planck Institutes.

A first on ultrafast phenomena in carbon nanostructures like graphene, the most promising candidate for revolutionizing information technology and communication The book introduces the reader into the ultrafast nanoworld of graphene and carbon nanotubes, including their microscopic tracks and unique optical finger prints. The author reviews the recent progress in this field by combining theoretical and experimental achievements. He offers a clear theoretical foundation by presenting transparently derived equations. Recent experimental breakthroughs are reviewed. By combining both theory and experiment as well as main results and detailed theoretical derivations, the book turns into an inevitable source for a wider audience from graduate students to researchers in physics, materials science, and electrical engineering who work on optoelectronic devices, renewable energies, or in the semiconductor industry.