Graphene Oxide

Often described as a “miracle material”, graphene’s potential applications are extraordinary, ranging from nanoscale ‘green’ technologies, to sensors and future conductive coatings. This book covers the topic of ‘graphene’ – the history, fundamental properties, methods of production and applications of this exciting new material. The style of the book is both scientific and technical – it is accessible to an audience that has a general, undergraduate-level background in the sciences or engineering, and is aimed at industries considering graphene applications. As the graphene topic is a broad-reaching and rapidly moving field of research, the aim of this book is therefore to provide information about graphene and its current and future applications that are immediately implementable, relevant and concise. After reading this book, the reader will have sufficient knowledge and background to move forward independently into graphene R&D and to apply the knowledge therein. Although the book will be self-contained, each chapter has copious references to enable further reading, research and exploration of the chapter topics.

What are the chemical aspects of graphene as a novel 2D material and how do they relate to the molecular structure? This book addresses these important questions from a theoretical and computational standpoint. Graphene Chemistry: Theoretical Perspectives presents recent exciting developments to correlate graphene’s properties and functions to its structure through state-of-the-art computational studies. This book focuses on the chemistry aspect of the structure-property relationship for many fascinating derivatives of graphene; various properties such as electronic structure, magnetism, and chemical reactivity, as well as potential applications in energy storage, catalysis, and nanoelectronics are covered. The book also includes two chapters with significant experimental portions, demonstrating how deep insights can be obtained by joint experimental and theoretical efforts. Topics covered include: Graphene ribbons: Edges, magnetism, preparation from unzipping, and electronic transport Nanographenes: Properties, reactivity, and synthesis Clar sextet rule in nanographene and graphene nanoribbons Porous graphene, nanomeshes, and graphene-based architecture and assemblies Doped graphene: Theory, synthesis, characterization and applications Mechanisms of graphene growth in chemical vapor deposition Surface adsorption and functionalization of graphene Conversion between graphene and graphene oxide Applications in gas separation, hydrogen storage, and catalysis Graphene Chemistry: Theoretical Perspectives provides a useful overview for computational and theoretical chemists who are active in this field and those who have not studied graphene before. It is also a valuable resource for experimentalist scientists working on graphene and related materials, who will benefit from many concepts and properties discussed here.

Graphene Materials: Fundamentals and Emerging Applications brings together innovative methodologies with research and development strategies to provide a detailed state-of-the-art overview of the processing, properties, and technology developments of graphene materials and their wide-ranging applications. The applications areas covered are biosensing, energy storage, environmental monitoring, and health. The book discusses the various methods that have been developed for the preparation and functionalization of single-layered graphene nanosheets. These form the essential building blocks for the bottom-up architecture of various graphene materials because they possess unique physico-chemical properties such as large surface areas, good conductivity and mechanical strength, high thermal stability and desirable flexibility. The electronic behavior in graphene, such as dirac fermions obtained due to the interaction with the ions of the lattice, has led to the discovery of novel miracles like Klein tunneling in carbon-based solid state systems and the so-called half-integer quantum Hall effect. The combination of these properties makes graphene a highly desirable material for applications. In particular, Graphene Materials: Fundamentals and Emerging Applications has chapters covering: • Graphene and related two-dimensional nanomaterials • Surface functionalization of graphene • Functional three-dimensional graphene networks • Covalent graphene-polymer nanocomposites • Magnesium matrix composites reinforced with graphene nanoplatelets • Graphene derivatives for energy storage • Graphene nanocomposite for high performance supercapacitors • Graphene nanocomposite-based bulk hetro-junction solar cells • Graphene bimetallic nanocatalysts foam for energy storage and biosensing • Graphene nanocomposites-based for electrochemical sensors • Graphene electrodes for health and environmental monitoring

Filling the gap between publications for industrial developers and academic researchers on graphene synthesis and its applications, this book presents the essential aspects for the successful upscaling of graphene production. After an introduction to graphene, its synthesis and characterization, the text covers a wide variety of graphene composites and compounds. The larger part of the book discusses various applications where graphene has been successfully integrated into technologies, including uses in the energy sector, oil and gas industry, biomedical areas, sensors and coatings. Finally, the book concludes with a summary and a look at the future of graphene technology, including a market review. With its focus on applications, this is equally useful for both academic and industrial users.

Metal Oxide Nanocomposites: Synthesis and Applications summarizes many of the recent research accomplishments in the area of metal oxide-based nanocomposites. This book focussing on the following topics: Nanocomposites preparation and characterization of metal oxide nanocomposites; synthesis of core/shell metal oxide nanocomposites; multilayer thin films; sequential assembly of nanocomposite materials; semiconducting polymer metal oxide nanocomposites; graphene-based metal and metal oxide nanocomposites; carbon nanotube–metal–oxide nanocomposites; silicon mixed oxide nanocomposites; gas semiconducting sensors based on metal oxide nanocomposites; metal9;]organic framework nanocomposite for hydrogen production and nanocomposites application towards photovoltaic and photocatalytic.

A wealth of information in one accessible book. Written by international experts from multidisciplinary fields, this in-depth exploration of oxide ultrathin films covers all aspects of these systems, starting with preparation and characterization, and going on to geometrical and electronic structure, as well as applications in current and future systems and devices. From the Contents: Synthesis and Preparation of Oxide Ultrathin Films Characterization Tools of Oxide Ultrathin Films Ordered Oxide Nanostructures on Metal Surfaces Unusual Properties of Oxides and Other Insulators in the Ultrathin Limit Silica and High-K Dielectrics Thin Films in Microelectronics Oxide Passive Films and Corrosion Protection Oxide Films as Catalytic Materials and as Models of Real Catalysts Oxide Films in Spintronics Oxide Ultrathin Films in Solid Oxide Fuel Cells Transparent Conducting and Chromogenic Oxide Films as Solar Energy Materials Oxide Ultrathin Films in Sensor Applications Ferroelectricity in Ultrathin Film Capacitors Titania Thin Films in Biocompatible Materials and Medical Implants Oxide Nanowires for New Chemical Sensor Devices

This first book dedicated to the topic provides an up-to-date account of the many opportunities graphene offers for robust, workable energy generation and storage devices. Following a brief overview of the fundamentals of graphene, including the main synthesis techniques, characterization methods and properties, the first part goes on to deal with graphene for energy storage applications, such as lithium-ion batteries, supercapacitors and hydrogen storage. The second part is concerned with graphene-based energy-generation devices, in particular conventional as well as microbial and enzymatic fuel cells, with chapters on graphene photovoltaics rounding off the book. Throughout, device architectures are not only discussed on a laboratory scale, but also ways for upscaling to an industrial level, including manufacturing processes and quality control. By bridging academic research and industrial development this is invaluable reading for materials scientists, physical chemists, electrochemists, solid state physicists, and those working in the electrotechnical industry.

Transparent electronics is emerging as one of the most promising technologies for the next generation of electronic products, away from the traditional silicon technology. It is essential for touch display panels, solar cells, LEDs and antistatic coatings. The book describes the concept of transparent electronics, passive and active oxide semiconductors, multicomponent dielectrics and their importance for a new era of novel electronic materials and products. This is followed by a short history of transistors, and how oxides have revolutionized this field. It concludes with a glance at low-cost, disposable and lightweight devices for the next generation of ergonomic and functional discrete devices. Chapters cover: Properties and applications of n-type oxide semiconductors P-type conductors and semiconductors, including copper oxide and tin monoxide Low-temperature processed dielectrics n and p-type thin film transistors (TFTs) – structure, physics and brief history Paper electronics – Paper transistors, paper memories and paper batteries Applications of oxide TFTs – transparent circuits, active matrices for displays and biosensors Written by a team of renowned world experts, Transparent Oxide Electronics: From Materials to Devices gives an overview of the world of transparent electronics, and showcases groundbreaking work on paper transistors

Since its discovery in 2004, graphene has been a great sensation due to its unique structure and unusual properties, and it has only taken 6 years for a Noble Prize to be awarded for the field of graphene research. This monograph gives a well-balanced overview on all areas of scientific interest surrounding this fascinating nanocarbon. In one handy volume it offers comprehensive coverage of the topic, including chemical, materials science, nanoscience, physics, engineering, life science, and potential applications. Other graphene-like, inorganic layered materials are also discussed. Edited by two highly honored scientists, this is an invaluable companion for inorganic, organic, and physical chemists, materials scientists, and physicists. From the Contents: * Synthesis, Characterization, and Selected Properties of Graphene * Understanding Graphene via Raman Scattering * Physics of Quanta and Quantum Fields in Graphene * Graphene and Graphene-Oxide-Based Materials for Electrochemical Energy Systems * Heterogeneous Catalysis by Metal Nanoparticles supported on Graphene * Graphenes in Supramolecular Gels and in Biological Systems and many more

The first book of its kind?providing comprehensive information on oxide thermoelectrics This timely book explores the latest research results on the physics and materials science of oxide thermoelectrics at all scales. It covers the theory, design and properties of thermoelectric materials as well as fabrication technologies for devices and their applications. Written by three distinguished materials scientists, Oxide Thermoelectric Materials reviews: the fundamentals of electron and phonon transport; modeling of thermoelectric modules and their optimization; synthetic processes, structures, and properties of thermoelectric materials such as Bi2Te3- and skutterudite-based materials and Si-Ge alloys. In addition, the book provides a detailed description of the construction of thermoelectric devices and their applications. -Contains fundamentals and applications of thermoelectric materials and devices, and discusses their near-future perspectives -Introduces new, promising materials and technologies, such as nanostructured materials, perovskites, and composites -Paves the way for increased conversion efficiencies of oxides -Authored by well-known experts in the field of thermoelectrics Oxide Thermoelectric Materials is a well-organized guidebook for graduate students involved in physics, chemistry, or materials science. It is also helpful for researchers who are getting involved in thermoelectric research and development.