Heterogeneous Catalysis at Nanoscale for Energy Applications

This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts.

An integrated approach to the molecular theory of reaction mechanism in heterogeneous catalysis, largely based on the knowledge among the growing theoretical catalysis community over the past half century, and covering all major catalytic systems. The authors develop a general conceptual framework, including in-depth comparisons with enzyme catalysis, biomineralisation, organometallic and coordination chemistry. A chapter dedicated to molecular electrocatalysis addresses the molecular description of reactions at the liquid-solid interphase, while studies range from a quantum-chemical treatment of individual molecular states to dynamic Monte-Carlo simulations, including the full flexibility of the many-particle systems. Complexity in catalysis is explained in chapters on self-organization and self-assembly of catalysts, and other sections are devoted to evolutionary, combinatorial techniques as well as artificial chemistry.

Written by one of the world's leading experts on the topic, this advanced textbook is the perfect introduction for newcomers to this exciting field. Concise and clear, the text focuses on such key aspects as kinetics, reaction mechanism and surface reactivity, concentrating on the essentials. The author also covers various catalytic systems, catalysis by design, and activation-deactivation. A website with supplementary material offers additional figures, original material and references.

Highlighting sustainable catalytic processes in synthetic organic chemistry and industry, this useful guide places special emphasis on catalytic reactions carried out at room temperature. It describes the fundamentals, summarizes key advances, and covers applications in industrial processes in the field of energy generation from renewables, food science, and pollution control. Throughout, the latest research from various disciplines is combined, such as homogeneous and heterogeneous catalysis, biocatalysis, and photocatalysis. The book concludes with a chapter on future trends and energy challenges for the latter half of the 21st century. With its multidisciplinary approach this is an essential reference for academic and industrial researchers in catalysis science aiming to design more sustainable and energy-efficient processes.

This book is based on a graduate course and suitable as a primer for any newcomer to the field, this book is a detailed introduction to the experimental and computational methods that are used to study how solid surfaces act as catalysts. Features include: First comprehensive description of modern theory of heterogeneous catalysis Basis for understanding and designing experiments in the field Allows reader to understand catalyst design principles Introduction to important elements of energy transformation technology Test driven at Stanford University over several semesters

Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.

This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved.

A multidisciplinary approach that explores the diverse properties, functions, and applications of nanomaterials Drawing together the many scientific and engineering disciplines underlying the development of nanomaterials, Nanoscale Multifunctional Materials provides a multidisciplinary review of the diverse properties, functions, and applications of nanomaterials. The book examines both nanoparticles, which have larger-scale equivalents, and uniquely assembled nanomaterials, which do not have larger-scale equivalents. Readers will gain a tremendous appreciation of the versatility of nanomaterials as well as an understanding of how the same nanomaterial can have several distinct applications across a broad range of fields and industries. Nanoscale Multifunctional Materials is divided into three sections: ? Section I, Overview, describes the scientific phenomena underlying the special properties of nanomaterials, making them desirable as novel materials and different from conventional solids. Next, readers will learn about the effect of nanomaterials on contemporary society as well as future trends in nanomaterials production and use. ? Section II, Processing and Analysis, explores several experimental approaches in nanomaterial fabrication and characterization as well as in theoretical approaches in modeling and simulation. ? Section III, Applications, offers detailed examples of nanomaterial applications in alternative energy, thermal management, environmental cleanup, water treatment, and biomedicine. Each chapter has been written by one or more leading experts in the science, engineering, and application of nanomaterials. Within each chapter, readers will find a thorough review of the current literature, with references to facilitate further investigation of individual topics. Underscoring the multidisciplinary and multifunctional characteristics of nanomaterials, this book is recommended for students and professionals in science and engineering who need a broad perspective on both the nature and application of nanomaterials. The text also sets the stage for the development of new nanomaterials and new applications.

A multidisciplinary approach that explores the diverse properties, functions, and applications of nanomaterials Drawing together the many scientific and engineering disciplines underlying the development of nanomaterials, Nanoscale Multifunctional Materials provides a multidisciplinary review of the diverse properties, functions, and applications of nanomaterials. The book examines both nanoparticles, which have larger-scale equivalents, and uniquely assembled nanomaterials, which do not have larger-scale equivalents. Readers will gain a tremendous appreciation of the versatility of nanomaterials as well as an understanding of how the same nanomaterial can have several distinct applications across a broad range of fields and industries. Nanoscale Multifunctional Materials is divided into three sections: ? Section I, Overview, describes the scientific phenomena underlying the special properties of nanomaterials, making them desirable as novel materials and different from conventional solids. Next, readers will learn about the effect of nanomaterials on contemporary society as well as future trends in nanomaterials production and use. ? Section II, Processing and Analysis, explores several experimental approaches in nanomaterial fabrication and characterization as well as in theoretical approaches in modeling and simulation. ? Section III, Applications, offers detailed examples of nanomaterial applications in alternative energy, thermal management, environmental cleanup, water treatment, and biomedicine. Each chapter has been written by one or more leading experts in the science, engineering, and application of nanomaterials. Within each chapter, readers will find a thorough review of the current literature, with references to facilitate further investigation of individual topics. Underscoring the multidisciplinary and multifunctional characteristics of nanomaterials, this book is recommended for students and professionals in science and engineering who need a broad perspective on both the nature and application of nanomaterials. The text also sets the stage for the development of new nanomaterials and new applications.