Lithium Batteries

Rechargeable Batteries with high energy density are in great demand as energy sources for various purposes, e.g. handies, zero emission electric vehicles, or load leveling in electric power. Lithium batteries are the most promising to fulfill such needs because of their intrinsic discharbe voltage with relatively light weight. This volume has been conceived keeping in mind selected fundamental topics together with the characteristics of the lithium ion battery on the market. It is thus a comprehensive overview of the new challenges facing the further development of lithium ion batteries from the standpoint of both materials science and technology. It will be useful for any scientist involved in the research and development of batteries in academia and industry, and also for graduate students entering the field, since it covers important topics from both fundamental and application points of view.

Lithium batteries were introduced relatively recently in comparison to lead- or nickel-based batteries, which have been around for over 100 years. Nevertheless, in the space of 20 years, they have acquired a considerable market share – particularly for the supply of mobile devices. We are still a long way from exhausting the possibilities that they offer. Numerous projects will undoubtedly further improve their performances in the years to come. For large-scale storage systems, other types of batteries are also worthy of consideration: hot batteries and redox flow systems, for example. This book begins by showing the diversity of applications for secondary batteries and the main characteristics required of them in terms of storage. After a chapter presenting the definitions and measuring methods used in the world of electrochemical storage, and another that gives examples of the applications of batteries, the remainder of this book is given over to describing the batteries developed recently (end of the 20th Century) which are now being commercialized, as well as those with a bright future. The authors also touch upon the increasingly rapid evolution of the technologies, particularly regarding lithium batteries, for which the avenues of research are extremely varied. Contents Part 1. Storage Requirements Characteristics of Secondary Batteries Examples of Use 1. Breakdown of Storage Requirements. 2. Definitions and Measuring Methods. 3. Practical Examples Using Electrochemical Storage. Part 2. Lithium Batteries 4. Introduction to Lithium Batteries. 5. The Basic Elements in Lithium-ion Batteries: Electrodes, Electrolytes and Collectors. 6. Usual Lithium-ion Batteries. 7. Present and Future Developments Regarding Lithium-ion Batteries. 8. Lithium-Metal Polymer Batteries. 9. Lithium-Sulfur Batteries. 10. Lithium-Air Batteries. 11. Lithium Resources. Part 3. Other Types of Batteries 12. Other Types of Batteries. About the Authors Christian Glaize is Professor at the University of Montpellier, France. He is also Researcher in the Materials and Energy Group (GEM) of the Institute for Electronics (IES), France. Sylvie Geni?s is a project manager at the French Alternative Energies and Atomic Energy Commission (Commissariat ? l’Energie Atomique et aux Energies Alternatives) in Grenoble, France.

Lithium secondary batteries have been key to mobile electronics since 1990. Large-format batteries typically for electric vehicles and energy storage systems are attracting much attention due to current energy and environmental issues. Lithium batteries are expected to play a central role in boosting green technologies. Therefore, a large number of scientists and engineers are carrying out research and development on lithium secondary batteries. The book is written in a straightforward fashion suitable for undergraduate and graduate students, as well as scientists, and engineers starting out in the field. The chapters in this book have been thoroughly edited by a collective of experts to achieve a cohesive book with a consistent style, level, and philosophy. They cover a wide range of topics, including principles and technologies of key materials such as the cathode, anode, electrolyte, and separator. Battery technologies such as design, manufacturing processes, and evaluation methods as well as applications are addressed. In addition, analytical methods for determining electrochemical and other properties of batteries are also included. Hence, this book is a must-have for everyone interested in obtaining all the basic information on lithium secondary batteries.

A comprehensive guide to the reuse and recycling of lithium-ion power batteries—fundamental concepts, relevant technologies, and business models Reuse and Recycling of Lithium-Ion Power Batteries explores ways in which retired lithium ion batteries (LIBs) can create long-term, stable profits within a well-designed business operation. Based on a large volume of experimental data collected in the author’s lab, it demonstrates how LIBs reuse can effectively cut the cost of Electric Vehicles (EVs) by extending the service lifetime of the batteries. In addition to the cost benefits, Dr. Guangjin Zhao discusses how recycling and reuse can significantly reduce environmental and safety hazards, thus complying with the core principles of environment protection: recycle, reuse and reduce. Offering coverage of both the fundamental theory and applied technologies involved in LIB reuse and recycling, the book's contents are based on the simulated and experimental results of a hybrid micro-grid demonstration project and recycling system. In the opening section on battery reuse, Dr. Zhao introduces key concepts, including battery dismantling, sorting, second life prediction, re-packing, system integration and relevant technologies. He then builds on that foundation to explore advanced topics, such as resource recovery, harmless treatment, secondary pollution control, and zero emissions technologies. Reuse and Recycling of Lithium-Ion Power Batteries: • Provides timely, in-depth coverage of both the reuse and recycling aspects of lithium-ion batteries • Is based on extensive simulation and experimental research performed by the author, as well as an extensive review of the current literature on the subject • Discusses the full range of critical issues, from battery dismantling and sorting to secondary pollution control and zero emissions technologies • Includes business models and strategies for secondary use and recycling of power lithium-ion batteries Reuse and Recycling of Lithium-Ion Power Batteries is an indispensable resource for researchers, engineers, and business professionals who work in industries involved in energy storage systems and battery recycling, especially with the manufacture and use (and reuse) of lithium-ion batteries. It is also a valuable supplementary text for advanced undergraduates and postgraduate students studying energy storage, battery recycling, and battery management.

This proceedings focuses on both the scientific and technological aspects of fuel cells and high energy density batteries including solid oxide; proton exchange membrane; and direct methanol fuel cells; lithium-ion batteries; oxide-ion electrolytes; proton conductors; mixed ionic-electronic conductors; electrocatalysts; new materials development; and other related solid state and electrochemical aspects including supercapacitors and oxygen separation membranes.

A theoretical and technical guide to the electric vehicle lithium-ion battery management system Covers the timely topic of battery management systems for lithium batteries. After introducing the problem and basic background theory, it discusses battery modeling and state estimation. In addition to theoretical modeling it also contains practical information on charging and discharging control technology, cell equalisation and application to electric vehicles, and a discussion of the key technologies and research methods of the lithium-ion power battery management system. The author systematically expounds the theory knowledge included in the lithium-ion battery management systems and its practical application in electric vehicles, describing the theoretical connotation and practical application of the battery management systems. Selected graphics in the book are directly derived from the real vehicle tests. Through comparative analysis of the different system structures and different graphic symbols, related concepts are clear and the understanding of the battery management systems is enhanced. Contents include: key technologies and the difficulty point of vehicle power battery management system; lithium-ion battery performance modeling and simulation; the estimation theory and methods of the lithium-ion battery state of charge, state of energy, state of health and peak power; lithium-ion battery charge and discharge control technology; consistent evaluation and equalization techniques of the battery pack; battery management system design and application in electric vehicles. A theoretical and technical guide to the electric vehicle lithium-ion battery management system Using simulation technology, schematic diagrams and case studies, the basic concepts are described clearly and offer detailed analysis of battery charge and discharge control principles Equips the reader with the understanding and concept of the power battery, providing a clear cognition of the application and management of lithium ion batteries in electric vehicles Arms audiences with lots of case studies Essential reading for Researchers and professionals working in energy technologies, utility planners and system engineers.

Offers the first comprehensive account of this interesting and growing research field Printed Batteries: Materials, Technologies and Applications reviews the current state of the art for printed batteries, discussing the different types and materials, and describing the printing techniques. It addresses the main applications that are being developed for printed batteries as well as the major advantages and remaining challenges that exist in this rapidly evolving area of research. It is the first book on printed batteries that seeks to promote a deeper understanding of this increasingly relevant research and application area. It is written in a way so as to interest and motivate readers to tackle the many challenges that lie ahead so that the entire research community can provide the world with a bright, innovative future in the area of printed batteries. Topics covered in Printed Batteries include, Printed Batteries: Definition, Types and Advantages; Printing Techniques for Batteries, Including 3D Printing; Inks Formulation and Properties for Printing Techniques; Rheological Properties for Electrode Slurry; Solid Polymer Electrolytes for Printed Batteries; Printed Battery Design; and Printed Battery Applications. Covers everything readers need to know about the materials and techniques required for printed batteries Informs on the applications for printed batteries and what the benefits are Discusses the challenges that lie ahead as innovators continue with their research Printed Batteries: Materials, Technologies and Applications is a unique and informative book that will appeal to academic researchers, industrial scientists, and engineers working in the areas of sensors, actuators, energy storage, and printed electronics.

This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes – with the development of ionic liquid-based electrolytes – is also explored.

Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.