Ions in Solution and their Solvation

Featuring contributions respected leaders in the field, Nitrene and Nitrenium Ions is the first comprehensive book to explore the role of reactive intermediate nitrene and nitrenium ions in chemistry and biochemistry. Covering a broad range of topics, including ultrafast studies, computational studies, behavior in aqueous solution, electronic structures, and reactions with aromatic compounds, this valuable resource will empower graduate students and researchers to better understand and expand their synthetic utility.

This comprehensive book presents the theoretical principles, current applications and latest research developments in the field of luminescent lanthanide complexes; a rapidly developing area of research which is attracting increasing interest amongst the scientific community. Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials begins with an introduction to the basic theoretical and practical aspects of lanthanide ion luminescence, and the spectroscopic techniques used to evaluate the efficiency of luminescence. Subsequent chapters introduce a variety of different applications including: • Circularly polarized luminescence • Luminescence bioimaging with lanthanide complexes • Two-photon absorption of lanthanide complexes • Chemosensors • Upconversion luminescence • Excitation spectroscopy • Heterometallic complexes containing lanthanides Each chapter presents a detailed introduction to the application, followed by a description of experimental techniques specific to the area and an extensive review of recent literature. This book is a valuable introduction to the literature for scientists new to the field, as well as providing the more experienced researcher with a comprehensive resource covering the most relevant information in the field; a ‘one stop shop’ for all key references.

Biofuels production is one of the most extensively studied fields in the energy sector that can provide an alternative energy source and bring the energy industry closer to sustainability. Biomass-based fuel production, or renewable fuels, are becoming increasingly important as a potential solution for man-made climate change, depleted oil reserves, and the dangers involved with hydraulic fracturing (or “fracking”). The price of oil will always be volatile and changeable, and, as long as industry and private citizens around the world need energy, there will be a need for alternative energy sources. The area known as “biofuels and biofeedstocks” is one of the most important and quickly growing pieces of the “energy pie.” But biofuels and biofeedstocks are constantly changing, and new processes are constantly being created, changed, and improved upon. The area is rapidly changing and always innovative. It is important, therefore, that books like the volumes in this series are published and the information widely disseminated to keep the industry informed of the state-of-the-art. This first volume in this groundbreaking new series is a collection of papers from some of the world’s foremost authorities on biofeedstocks and biofuels, covering biofeedstocks and how they are processed. It is a must-have for any engineer, scientist, technician, or student working in this area.

Superelectrophiles and Their Chemistry contains, for the first-time, a discussion of the basics of this emerging field of organic chemistry, alongside tools to help the reader apply the chemistry. Specific tools include an evaluation of the ways to increase the strength of electrophiles, the classification of superelectrophiles, the solvation issues, a review of methods for studying superelectrophilicity, with details of the superelectrophiles that have been identified and studied. Additional information includes substituent effects in activation of superelectrophiles, and solvation in chemical reactions, as well as an insightful look into future applications.

Long-awaited on the importance of halogen bonding in solution, demonstrating the specific advantages in various fields – from synthesis and catalysis to biochemistry and electrochemistry! Halogen bonding (XB) describes the interaction between an electron donor and the electrophilic region of a halogen atom. Its applicability for molecular recognition processes long remained unappreciated and has mostly been studied in solid state until recently. As most physiological processes and chemical reactions take place in solution, investigations in solutions are of highest relevance for its use in organic synthesis and catalysis, pharmaceutical chemistry and drug design, electrochemistry, as well as material synthesis. Halogen Bonding in Solution gives a concise overview of halogen bond interactions in solution. It discusses the history and electronic origin of halogen bonding and summarizes all relevant examples of its application in organocatalysis. It describes the use of molecular iodine in catalysis and industrial applications, as well as recent developments in anion transport and binding. Hot topic: Halogen bonding is an important interaction between molecules or within a molecule. The field has developed considerably in recent years, with numerous different approaches and applications having been published. Unique: There are several books on halogen bonding in solid state available, but this will be the first one focused on halogen bonding in solution. Multi-disciplinary: Summarizes the history and nature of halogen bonding in solution as well as applications in catalysis, anion recognition, biochemistry, and electrochemistry. Aimed at facilitating exciting future developments in the field, Halogen Bonding in Solution is a valuable source of information for researchers and professionals working in the field of supramolecular chemistry, catalysis, biochemistry, drug design, and electrochemistry.

Divided into two parts, the first four chapters of Comets and their Origin refer to comets and their formation in general, describing cometary missions, comet remote observations, astrochemistry, artificial comets, and the chirality phenomenon. The second part covers the cometary ROSETTA mission, its launch, journey, scientific objectives, and instrumentations, as well as the landing scenario on a cometary nucleus. Along the way, the author presents general questions concerning the origin of terrestrial water and the molecular beginnings of life on Earth, as well as how the instruments used on a space mission like ROSETTA can help answer them. The text concludes with a chapter on what scientists expect from the ROSETTA mission and how its data will influence our life on Earth. As a result, the author elucidates highly topical and fascinating knowledge to scientists and students of various scientific backgrounds, allowing them to work with ROSETTA's data.

Written by the pioneers of Viagra, the first blockbuster PDE inhibitor drug. Beginning with a review of the first wave of phosphodiesterase (PDE) inhibitors, this book focuses on new and emerging PDE targets and their inhibitors. Drug development options for all major human PDE families are discussed and cover diverse therapeutic fields, such as neurological/psychiatric, cardiovascular/metabolic, pain, and allergy/respiratory diseases. Finally, emerging chemotherapeutic applications of PDE inhibitors against malaria and other tropical diseases are discussed.

From the reviews of Numerical Solution of Partial Differential Equations in Science and Engineering: «The book by Lapidus and Pinder is a very comprehensive, even exhaustive, survey of the subject . . . [It] is unique in that it covers equally finite difference and finite element methods.» Burrelle's «The authors have selected an elementary (but not simplistic) mode of presentation. Many different computational schemes are described in great detail . . . Numerous practical examples and applications are described from beginning to the end, often with calculated results given.» Mathematics of Computing «This volume . . . devotes its considerable number of pages to lucid developments of the methods [for solving partial differential equations] . . . the writing is very polished and I found it a pleasure to read!» Mathematics of Computation Of related interest . . . NUMERICAL ANALYSIS FOR APPLIED SCIENCE Myron B. Allen and Eli L. Isaacson. A modern, practical look at numerical analysis, this book guides readers through a broad selection of numerical methods, implementation, and basic theoretical results, with an emphasis on methods used in scientific computation involving differential equations. 1997 (0-471-55266-6) 512 pp. APPLIED MATHEMATICS Second Edition, J. David Logan. Presenting an easily accessible treatment of mathematical methods for scientists and engineers, this acclaimed work covers fluid mechanics and calculus of variations as well as more modern methods-dimensional analysis and scaling, nonlinear wave propagation, bifurcation, and singular perturbation. 1996 (0-471-16513-1) 496 pp.

Soil Properties and their Correlations, Second Edition Michael Carter, Geotechnical Consultant (Retired), UK Stephen P Bentley, Reader in Engineering Geology, Cardiff University, UK An essential guide to improving preliminary geotechnical analysis and design from limited data Soil Properties and their Correlations, Second Edition provides a summary of commonly-used soil engineering properties and gives a wide range of correlations between the various properties, presented in the context of how they will be used in geotechnical design. The book is divided into 11 chapters: Commonly-measured properties; Grading and plasticity; Density; Permeability, Consolidation and settlement; Shear strength; California bearing ratio; Shrinkage and swelling characteristics; Frost susceptibility; Susceptibility to combustion; and Soil-structure interfaces. In addition, there are two appendices: Soil classification systems; and Sampling methods. This new, more comprehensive, edition provides material that would be of practical assistance to those faced with the problem of having to estimate soil behaviour from little or no laboratory test data. Key features: • Soil properties explained in practical terms. • A large number of correlations between different soil properties. • A valuable aid for assessing design values of properties. • Clear statements on practical limitations and accuracy. An invaluable source of reference for experienced professionals working on geotechnical design, it will also give students and early-career engineers an in-depth appreciation of the appropriate use of each property and the pitfalls to avoid.

The integration of machine learning techniques and cartoon animation research is fast becoming a hot topic. This book helps readers learn the latest machine learning techniques, including patch alignment framework; spectral clustering, graph cuts, and convex relaxation; ensemble manifold learning; multiple kernel learning; multiview subspace learning; and multiview distance metric learning. It then presents the applications of these modern machine learning techniques in cartoon animation research. With these techniques, users can efficiently utilize the cartoon materials to generate animations in areas such as virtual reality, video games, animation films, and sport simulations